Let us express that the magnitudes are equal. Using the classical formula:
$$\left|\frac{-b+\sqrt{b^2-4ac}}{2a}\right|=\left|\frac{-b-\sqrt{b^2-4ac}}{2a}\right|.$$
If $b=0$, the equality holds.
Otherwise, we can multiply by $|-2a/b|$, and
$$\left|1-\sqrt{1-4\frac{ac}{b^2}}\right|=\left|1+\sqrt{1-4\frac{ac}{b^2}}\right|.$$
Now, $|1-p|=|1+p|\implies \Re(p)=0$. Indeed, $(1-x)^2+y^2=(1+x)^2+y^2\implies x=0$.
So
$$\sqrt{1-4\frac{ac}{b^2}}=iy,$$
$$ac=\frac{1-y^2}4b^2.$$
In conclusion, the magnitudes differ if $b$ is nonzero and $ac$ is not the product of $b^2$ by a real number less than or equal to $1/4$.