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Show that $$\sum_{k=0}^n(-1)^k\binom nk=0$$ So for odd $n$ we have an even number of terms. So $\binom nk=\binom n{n-k}$ which have opposite signs. Thus the sum is 0.
For even $n$ we have that $$\sum_{k=0}^n(-1)^k\binom nk= \binom n0+\sum_{k=1}^{n-1}(-1)^k\binom nk+\binom nn$$ Now $$\sum_{k=1}^{n-1}(-1)^k\binom nk= \sum_{k=1}^{n-1}(-1)^k\left[\binom{n-1}k+\binom{n-1}{k-1}\right]$$ What would that sum be in the square brackets?
Here is an alternate way:
$$0=(1-1)^n=\sum_{k=0}^{n} (-1)^{k} \binom{n}{k}$$
by the binomial theorem.
Another way for combinatorially-minded people:
$$\sum_{k=0}^n (-1)^k \binom{n}{k} = 0$$
is the number of ways to flip n coins and get an even number of heads, minus the number of ways to flip n coins and get an odd number of heads. Since the parity of the number of heads will always come down to the last coin flipped, and heads/tails are of course equally likely at that point, the sum evaluates to 0.
You should know that $$ (a+b)^n=\sum_{k=0}^n \binom nk a^kb^{n-k}. $$ When $b=1$, this says $$ (1+a)^n=\sum_{k=0}^n \binom nk a^k. $$ So now you just need to consider the case where $a=-1$.
For odd $n$, the OP gave a bijective proof of the result. The following is a bijective proof that works for all $n$.
Let $A=\{1,2,\dots, n\}$. Let $\mathcal{E}$ consist of the subsets of $A$ of even cardinality, and let $\mathcal{O}$ consist of the subsets of $A$ of odd cardinality. We produce an explicit bijection $\varphi: \mathcal{E} \to \mathcal{O}$.
If $S\in \mathcal{E}$ and $1\notin S$, let $\varphi(S)=S\cup\{1\}$.
If $S\in \mathcal{E}$ and $1\in S$, let $\varphi(S)=S\setminus\{1\}$.
Comment: For the sake of symmetry, it is probably better to define $\varphi(S)$ as above, but for any subset $S$ of $A$. Then $\varphi$ is an involution on $P(A)$ that interchanges sets of even cardinality with sets of odd cardinality.
We have, since $n-1$ is odd \begin{align*}\sum_{k=1}^{n-1}(-1)^k\left[\binom{n-1}k+\binom{n-1}{k-1}\right]&=\sum_{k=1}^{n-1}(-1)^k\binom{n-1}k-\sum_{j=0}^{n-2}(-1)^j\binom{n-1}j\\ &=-1+\binom{n-1}{n-1}(-1)^{n-1}\\ &=-2, \end{align*} hence $$\sum_{k=0}^n\binom nk(-1)^k=\binom n0 -2+\binom nn =0.$$
$$0=(1-1)^n=\sum_{k=0}^n{n\choose k}(-1)^k$$
One can also give a topological proof of the binomial identity $\sum_{i=0} ^{n} (-1)^i \binom{n}{i}=0$. Consider the standard $(n-1)$-simplex $\Delta^{n-1}$. This has $\binom{n+1}{i+1}$ $i$-simplicies, hence the Euler characteristic of $\Delta^{n-1}$ is $$\chi(\Delta^{n-1})=\sum_{i=0} ^{n-1} (-1)^i \binom{n}{i+1}.$$
The Euler characteristic is homotopy invariant and $\Delta^{n-1}\simeq *$, so we must have
$$\sum_{i=0} ^{n-1} (-1)^i \binom{n}{i+1}=1,$$ or $$\sum_{i=0} ^{n-1} (-1)^i \binom{n}{i+1}-\binom{n}{0}=0$$ since $\binom{n}{0}=1$. Multiplying both sides by $-1$ yields the identity
$$\sum_{i=0} ^{n} (-1)^i \binom{n}{i}=0.$$
Another approach:
For the difference operator $\Delta f (m) = f(m+1)-f(m)$, the $n$th iteration is
$$\Delta^n f(m)=\sum_{k}(-1)^{n-k}\binom nk f(m+k)$$
Clearly, your sum is the $n$th difference of the constant function $f\equiv 1$, so of course it is zero for $n\ge 1$ because already $f(m+1)-f(m) =0 $.
