To show that $\mathbb{H}$ maps onto $\mathrm{Aut}(\mathbb{H})$, where $\mathbb{H}$ is the Hamilton quaternions, I thought it'd be pertinent to show first that the subgroup of inner automorphisms of $\mathbb{H}$ (which is in fact the entire group of automorphisms, since all the automorphisms end up being inner by Skolem-Noether, though I don't have enough knowledge of algebra to understand anything about this theorem other than its statement) acts transitively on purely imaginary unit quaternions; then to show that the stabilizer of one of these purely imaginary units-- say $i$-- acts transitively on all purely imaginary units orthogonal to it.
Finally, showing that fixing $i$ and some purely imaginary unit orthogonal to it gives only the trivial automorphism shows that all automorphisms are inner, and hence $\mathbb{H}^{*}$ maps onto $\mathrm{Aut}(\mathbb{H})$.
However I can't find an elegant way to solve the first two parts of this-- that is, a proof of this special case of Skolem-Noether with more elementary methods. Any hints would be appreciated.
EDIT: I realize that the purely imaginary quaternions give the unit sphere. Perhaps a proof along these steps using that would be helpful? What exactly would conjugation constitute on the unit sphere? What would an orthogonal unit mean on the unit sphere? Even answering these things would be very helpful.