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$\ds{\int_{-\infty}^{\infty}\bracks{\arctan\pars{x} \over x}^{2}\,\dd x
=2\pi\ln\pars{2}:\ {\large ?}}$
\begin{align}&\color{#66f}{\large\int_{-\infty}^{\infty}%
\bracks{\arctan\pars{x} \over x}^{2}\,\dd x}
=\int_{x\ \to\ -\infty}^{x\ \to\ \infty}
\arctan^{2}\pars{x}\,\dd\pars{-\,{1 \over x}}
\\[3mm]&=\int_{-\infty}^{\infty}
{1 \over x}\bracks{2\arctan\pars{x}\,{1 \over 1 + x^{2}}}\,\dd x
=2\,\Im\
\overbrace{\int_{-\infty}^{\infty}{\ln\pars{1 + x\ic} \over x\pars{1 + x^{2}}}
\,\dd x}^{\ds{\mbox{Set}\ 1 + x\ic \equiv t\ \imp\ x = \pars{1 - t}\ic}}
\\[3mm]&=2\,\Im\int_{1 - \infty\ic}^{1 + \infty\ic}
{\ln\pars{t} \over \pars{1 - t}\ic\pars{2 - t} t}\,\pars{-\ic\,\dd t}
=2\,\Im\int_{1 - \infty\ic}^{1 + \infty\ic}
{\ln\pars{t} \over t\pars{t - 1}\pars{t - 2}}\,\dd t
\\[3mm]&=2\,\Im\bracks{2\pi\ic\,{\ln\pars{2} + \ic 0^{+} \over 2\pars{2 - 1}}}
=\color{#66f}{\large 2\pi\ln\pars{2}} \approx {\tt 4.3552}
\end{align}
In the above calculation we took the $\ds{\ln}$-branch cut:
$$
\ln\pars{z} = \ln\pars{\verts{z}} + {\rm Arg}\pars{z}\ic\,,\quad\verts{{\rm Arg}\pars{z}} < \pi\,,\quad z \not= 0
$$
The integration path is closed with the arc
$\ds{\braces{\pars{x,y}\quad \mid\quad \pars{x - 1}^{2} + y^{2} = R^{2}\,,\quad
x \geq 1\,,\quad R > 1}}$ such that the 'arc contribution' vanishes out in the limit $\ds{R \to \infty}$.