Because $7$ is prime, we know that, $Aut(\mathbb{Q}[\zeta_7]/\mathbb{Q}) \cong \mathbb{Z}_7^\times \cong \mathbb{Z}_6$.
From here, we wish to find a generator for that automorphism group. Note that $\mathbb{Q}[\zeta_7]$ is the splitting field for the irreducible polynomial $f(x) = x^6 + x^5 + \cdots + x + 1$ whose roots are the $6$ nontrivial $7$th roots of unity. Now, it is a theorem that the automorphism group acts transitively on the roots of the polynomial $\iff$ that polynomial is irreducible. Therefore, we know there must exist an automorphism within this group such that $\zeta \mapsto \zeta^n$ for any $n \in \{1, 2, ..., 5\}$. The easiest way I know how to do this is through experimentation.
Once you've found your generator, $\phi$, then your automorphism group is simply $\{id, \phi, \phi^2, ..., \phi^5\}$.
The motivation behind all this work was that you need to let your entire automorphism group act on $\zeta + \zeta_5$ to generate the minimal polynomial. If we denote $\{\alpha_1, \alpha_2, ..., \alpha_k \}$ as the orbit of $\zeta + \zeta^5$ under this action, then the minimal polynomial will be be $m(x) = \displaystyle \prod_{i=1}^k\Big(x-\alpha_i\Big)$.
The moral of the story is that you had the right idea, but the previous sentence is where you went astray.
Edit: It is not necessary to actually find the generator, but it is necessary to let the entire automorphism group act on $\zeta + \zeta^5$. Note that there will be an automorphism that maps $\zeta \mapsto \zeta^k$ for all $k$ by the reasoning above, and each one must (obviously) be unique. Thus, the $6$ of them are:
- $\zeta \mapsto \zeta$
- $\zeta \mapsto \zeta^2$
- $\zeta \mapsto \zeta^3$
etc.
To conclude, if possible, I would recommend you find a copy of Artin and read Chapter 14, Section 4, Proposition 4.4. I think that would get to the crux of where you went wrong initially. You can find a .pdf version of this text here: http://www.drchristiansalas.org.uk/MathsandPhysics/AbstractAlgebra/ArtinAlgebra.pdf