If you've learned to represent forces by vectors, you can place, say, the 40-pound force on the positive $ \ x-$ axis, so that it is represented as $ \ 40 \ \hat{i} \ $ . The 28-pound force can then be set up as pointing in the direction 65º counterclockwise relative to the positive $ \ x-$ axis; it will then have an $ \ x-$ component of $ \ 28 \ \cos 65º \ \hat{i} \ $ and a $ \ y-$ component of $ \ 28 \ \sin 65º \ \hat{j} \ $ .
We then add the $ \ x- $ and $ \ y-$ components separately to find the resultant force represented as $$ \ ( \ 40 \ + \ 28 \ \cos 65º \ ) \hat{i} \ + \ 28 \ \sin 65º \ \hat{j} \ \approx \ 51.8 \hat{i} \ + \ 25.4 \ \hat{j} \ \ \text{lbs} \ \ . $$
These two components form the legs of a right triangle. The magnitude is found from the hypotenuse of that triangle, so we apply the Pythagorean Theorem. The angle $ \ \theta \ $ that the result makes to the positive $ \ x-$ axis is given by
$$ \tan \theta \ = \ \frac{\text{y-component}}{\text{x-component}} \ \approx \ \frac{25.4}{51.8} \ \ . $$
The size of the requested angle is the difference of that angle $ \ \theta \ $ from 65º .