One way to work this one out is to rewrite the integral as
$$\int_0^{\infty} dx \, \frac{x \, e^{-x}}{1+e^{-x}} $$
then expand the denominator in a Taylor series. The representation of this integral becomes
$$\int_0^{\infty} dx \, x \sum_{k=0}^{\infty} (-1)^k e^{-(k+1) x} $$
Because the sum and integral converge, we can change the order of summation and integration:
$$\sum_{k=0}^{\infty} (-1)^k \int_0^{\infty} dx \, x \, e^{-(k+1) x} = \sum_{k=0}^{\infty} \frac{(-1)^k}{(k+1)^2}$$
Another way to work this, which you may or may not be aware of, is to use Cauchy's theorem. Consider the contour integral
$$\oint_C dz \frac{z^2}{1+e^z} $$
where $C$ is the rectangle with vertices $0$, $R$, $R+i 2 \pi$, and $i 2 \pi$, with a semicircular segment of radius $\epsilon$ centered at $i \pi$ into the rectangle. The contour integral then becomes
$$\int_0^R dx \frac{x^2}{1+e^x} + i \int_0^{2 \pi} dy \frac{(R+i y)^2}{1+e^R e^{i y}} +\int_R^0 dx \frac{(x+i 2 \pi)^2}{1+e^x} \\ +i \int_{2 \pi}^{\pi+\epsilon} dy \frac{(i y)^2}{1+e^{i y}}+ i \epsilon \int_{\pi/2}^{-\pi/2} d\phi \, e^{i \phi} \frac{(i \pi+\epsilon e^{i \phi})^2}{1-e^{\epsilon e^{i \phi}}} + i \int_{\pi-\epsilon}^0 dy \frac{(i y)^2}{1+e^{i y}}$$
As $R\to\infty$, the second integral vanishes. As $\epsilon \to 0$, the fifth integral becomes
$$i \epsilon \int_{\pi/2}^{-\pi/2} d\phi \, e^{i \phi} \frac{-\pi^2}{-\epsilon e^{i \phi}} = -i \pi^3$$
The contour integral is then
$$-i 4 \pi \int_0^{\infty} dx \frac{x}{1+e^x} + 4 \pi^2 \int_0^{\infty} \frac{dx}{1+e^x} + i PV \int_0^{2 \pi} dy \frac{y^2}{1+e^{i y}}-i \pi^3$$
Note that $PV$ denotes the Cauchy principal value. Also note that
$$\begin{align}i PV \int_0^{2 \pi} dy \frac{y^2}{1+e^{i y}} &= i \frac12 \int_0^{2 \pi} dy \, y^2 + \frac12 PV \int_0^{2 \pi} dy \, y^2 \tan{\left ( \frac{y}{2}\right )}\\ &= i \frac{4 \pi^3}{3} + \frac12 PV \int_0^{2 \pi} dy \, y^2 \tan{\left ( \frac{y}{2}\right )} \end{align}$$
By Cauchy's theorem, the contour integral is zero, which means that both the real and imaginary parts are zero. From the imaginary part of the contour integral being zero, we have
$$\int_0^{\infty} dx \frac{x}{1+e^x} = \frac{\pi^2}{12} $$