Proof that the minimum value of the quadratic form $n^T A n$ is the minimum eigenvalue of a real symmetric matrix $A$ for a unit vector $n$:
Let $A=UDU^T$ be its eigen decomposition. Then $D$ is a diagonal matrix with all the eigenvalues as diagonal entries. Let $D_{ii} = \lambda_i$Then we have
\begin{align}
\min_{|n|=1}~n^TAn\\&=\min_{|n|=1}~n^T(UDU^T)n\\&=\min_{|n|=1}~(U^Tn)^TD(U^Tn)\\&=\min_{|U^Tn|=1}(U^Tn)^TD(U^Tn) ~~~\tag{1} \\
&=\min_{|y|=1}~y^TDy, y:=U^Tn\\
&=\min_{|y|=1}\sum_{i}y_i^2D_{ii}\\
&=\min_{|y|=1}\sum_{i}y_i^2 \lambda_{i}~~~~~~~~~
\end{align}
Let $\lambda_j := \min \{\lambda_1, ..., \lambda_n\} = \min_i \{\lambda_i\}$ for some $j = 1, ..., n$.
Observe the following lower bound for the quadratic form
$$\sum_{i}y_i^2 \lambda_{i} \ge \sum_{i}y_i^2 \lambda_j = \lambda_j \sum_{i}y_i^2 = \lambda_j (1) = \lambda_j \tag{2}$$
This is actually the greatest lower bound, i.e. infimum, because the RHS of $(2)$ does not depend on $y$: for any $y$, the quadratic form is greater than or equal to $\lambda_j$.
This is actually the minimum because the quadratic form can achieve the infimum for $y$ s.t. $y_j=1$ and $y_i=0$ for the $i$'s that aren't $j$ ($\forall \ i \ne j$).
QED
By the way if $A^T=A^{-1}$, then $\lambda_j=-1$ because Can we prove that the eigenvalues of an $n\times n$ orthogonal matrix are $\pm 1$ by only using the definition of orthogonal matrix?
$(1)$ Observe that $|U^Tn|=1$ because $|n|=1$.
Pf: $$|U^Tn|=(U^Tn)^T U^Tn = n^T U U^T n = n^T (I) n = n^T n = |n| = 1$$ QED