If a set of vectors is closed under addition, it means that if you perform vector addition on any two vectors within that set, the result is another vector within the set.
For instance, the set containing vectors of the form $<x, 2x>$ would be closed under vector addition. Adding two arbitrary vectors from this space, say $<x_1, 2x_1> + <x_2, 2x_2>$, results in $<x_1+x_2, 2(x_1+x_2)>$, which is also in the vector space (let $x = x_1+x_2$).
However, the set containing vectors of the form $<1, x>$ would not be closed under vector addition (add two arbitrary vectors from the set and you'll see that the resulting vector is $<2, x_1+x_2>$, which is not in the set, as $1\neq2$).