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$\ds{\int_{0}^{1}\arctan^{2}\pars{x}\,\dd x
={\pi^{2} \over 16} + {\pi\ln\pars{2} \over 4} - C:\ {\large ?}.\quad}$
$\ds{C}$ is the Catalan Constant.
Set $\ds{\quad x \equiv \tan\pars{\theta}\quad\imp\quad\theta = \arctan\pars{x}}$:
\begin{align}&\color{#c00000}{\int_{0}^{1}\arctan^{2}\pars{x}\,\dd x}
=\int_{0}^{\pi/4}\theta^{2}\sec^{2}\pars{\theta}\,\dd\theta
={\pi^{2} \over 16} - \int_{0}^{\pi/4}\tan\pars{\theta}\pars{2\theta}\,\dd\theta
\\[3mm]&={\pi^{2} \over 16} + \ln\pars{1 \over \root{2}}2\,{\pi \over 4} -2\int_{0}^{\pi/4}\ln\pars{\cos\pars{\theta}}\,\dd\theta
\\[3mm]&={\pi^{2} \over 16} - {1 \over 4}\,\pi\ln\pars{2} - \int_{0}^{\pi/4}
\ln\pars{\half\bracks{2\sin\pars{\theta}\cos\pars{\theta}}\cot\pars{\theta}}
\,\dd\theta
\\[3mm]&={\pi^{2} \over 16} - {1 \over 4}\,\pi\ln\pars{2}
+ {1 \over 4}\,\pi\ln\pars{2} - \int_{0}^{\pi/4}\ln\pars{\cot\pars{\theta}}\,\dd\theta
-\int_{0}^{\pi/4}\ln\pars{\sin\pars{2\theta}}\,\dd\theta
\end{align}
However, a integral representation of $\ds{C}$ is given by:
$$
C = \int_{0}^{\pi/4}\ln\pars{\cot\pars{\theta}}\,\dd\theta
$$
such that
$$
\color{#c00000}{\int_{0}^{1}\arctan^{2}\pars{x}\,\dd x}
={\pi^{2} \over 16} - C
-\half\color{#00f}{\int_{0}^{\pi/2}\ln\pars{\sin\pars{\theta}}\,\dd\theta}\tag{1}
$$
Also,
\begin{align}&\color{#00f}{\int_{0}^{\pi/2}\ln\pars{\sin\pars{\theta}}\,\dd\theta}
=\half\bracks{\int_{0}^{\pi/2}\ln\pars{\sin\pars{\theta}}\,\dd\theta
+\int_{0}^{\pi/2}\ln\pars{\cos\pars{\theta}}\,\dd\theta}
\\[3mm]&=\half\int_{0}^{\pi/2}\ln\pars{\sin\pars{2\theta} \over 2}\,\dd\theta
=-\,{1 \over 4}\,\pi\ln\pars{2}
+{1 \over 4}\int_{0}^{\pi}\ln\pars{\sin\pars{\theta}}\,\dd\theta
\\[3mm]&=-\,{1 \over 4}\,\pi\ln\pars{2}
+{1 \over 4}\int_{0}^{\pi/2}\ln\pars{\sin\pars{\theta}}\,\dd\theta
+{1 \over 4}\int_{\pi/2}^{\pi}\ln\pars{\sin\pars{\theta}}\,\dd\theta
\\[3mm]&=-\,{1 \over 4}\,\pi\ln\pars{2}
+\half\color{#00f}{\int_{0}^{\pi/2}\ln\pars{\sin\pars{\theta}}\,\dd\theta}
\end{align}
$$
\imp\quad\color{#00f}{\int_{0}^{\pi/2}\ln\pars{\sin\pars{\theta}}\,\dd\theta} = -\,\half\,\pi\ln\pars{2}
$$
Replace this result in $\pars{1}$:
$$\color{#66f}{\large%
\int_{0}^{1}\arctan^{2}\pars{x}\,\dd x
={\pi^{2} \over 16} + {\pi\ln\pars{2} \over 4} - C} \approx 0.2453
$$