Can I use the "Secretary Problem" to find the worst candidate, too? As you know, we use the "Secretary Problem" to choose the single best candidate. Now I would like to know can we use this rule to find the worst candidate, too? If yes, how to accomplish this?
 A: Yes. 
The algorithm simply finds the participant who is optimal according to some property, but does not care what that property means (as long as it defines an ordering relation on the candidates). Changing that property from being good to being bad (or whatever else) is just a definition without algorithmic relevance.
A: I think he wants to know if you can use the procedure to choose the worst (instead of the best) candidate. The answer is yes.
The situation is: you know how many candidates $N$ there are, but you don't know the distribution of the quality of the candidates. Also, you can only look at one candidate at a time, and not go back to a previous candidates ("no recall"). 
You use the $1/e$ algorithm: first look at $1/e$ of the $N$ candidates, and remember the quality of the worst of those, which is, say, $\underline{q}$. After the $N/e$ sampled candidates, you choose the first candidate that is worse than what you have previously seen, i.e., you choose candidate $i$ if $q_i\le \underline{q}$, and candidate $N$ if no candidate's quality was worse. This procedure maximizes the probability to choose the worst candidate. 
This is just the inversion of the solution to maximize the probability to choose the best candidate.
A: Sure, the algorithm will just choose a highly ranked candidate (probably). It's up to you how you rank them - by how good they are, or by how bad they are, the algorithm doesn't know what the ranking system means.
