Inscribe a hexagon of side 1 inside a circle of radius 1. Then the triangle inequality (with limits) shows that $6 < 2 \pi$.
There is an elementary proof (see Wikipedia) that $\pi < { 22 \over 7}$
(which is $<4$).
Alternative answer: (I feel the need to redeem myself :-).)
Micah's answer is far more succinct, but I like the following approach as it forges a link between the analytical and geometric aspects.
I am assuming that $\cos $ (and $\sin$) are defined using the usual power series, and $\pi$ is defined as in the question. Since $\sin' = \cos$, we see that $\sin$ is increasing (and hence positive) on $(0,{ \pi \over 2}]$.
By differentiating the function $x \mapsto \cos^2 x+ \sin^2 x$ and evaluating at $x=0$ we can establish the identity $\cos^2 x+ \sin^2 x = 1$. (This gives $\sin {\pi \over 2} = 1$.)
Similarly, by differentiating the function $x \mapsto (\cos x -\sin({\pi \over 2} -x))^2 + (\sin x -\cos({\pi \over 2} -x))^2$ we see that it is constant and by evaluating at $x=0$, we obtain the identities $\cos x =\sin({\pi \over 2} -x)$ and
$\sin x =\cos({\pi \over 2} -x)$.
From this we get $\cos { \pi \over 4} = \sin { \pi \over 4} = {1 \over \sqrt{2}}$.
If $\gamma:[0,1] \to \mathbb{R}^2$ is $C^1$, we define the length as $l(\gamma) = \sup_{{\cal P}} \sum_k | \gamma(t_{k+1}) -\gamma(t_k)|$, where ${\cal P}$ are the partitions of $[0,1]$ and we note that
$l(\gamma) = \int_0^1 \|\gamma'(t)\| dt$.
Now consider the curves $\lambda(t) = (1,0) + t ({1 \over \sqrt{2}}-1, {1 \over \sqrt{2}})$,
$\gamma(t) = (\cos (t { \pi \over 4}), \sin (t { \pi \over 4}))$, and
$\upsilon(t) = (1,0)+t (0,1)$.

We have $\|\lambda'(t)\| = \sqrt{2 -\sqrt{2}}$, $\|\gamma'(t)\| = {\pi \over 4}$, and $\|\upsilon'(t)\| =1$.
Note that for the straight lines $\lambda, \upsilon$, for any partition $(0=t_1,...,t_n=1)$ we have $l(\lambda) = \sum_k |\lambda(t_{k+1})-\lambda(t_k)|$, and similarly for $\upsilon$. In particular, for any strictly increasing continuous function $\eta:[0,1] \to [0,1]$ with $\eta(0) = 0, \eta(1) = 1$, we have $l(\upsilon) = l(\upsilon \circ \eta)$ (this is true more generally, of course).
We have $\lambda(0) = \gamma(0), \lambda(1) = \gamma(1)$, and taking any partition of the form $(0,t,1)$ with $t \in (0,1)$ we have $l(\gamma) = |\lambda(1)-\lambda(0)| = |\gamma(1)-\gamma(0)| < |\gamma(1)-\gamma(t)| + |\gamma(t)-\gamma(0)| \le l(\gamma)$, and so
$\sqrt{2 -\sqrt{2}} < {\pi \over 4}$. A little manipulation shows that $4(\sqrt{2 -\sqrt{2}}) >3$, which gives $\pi > 3$.
For the other bound, let $\eta(t) = {\sin (t { \pi \over 4}) \over \cos (t { \pi \over 4})}$, then we have $\eta'(t) = {\pi \over 4} {1 \over \cos ^2(t { \pi \over 4})}>0$, and $\|(\upsilon \circ \eta)'(t) \| = {\pi \over 4} {1 \over \cos ^2(t { \pi \over 4})}$. In particular, $\|\gamma'(t)\| < \|(\upsilon \circ \eta)'(t) \|$ for all $ t \in (0,1]$. It follows that $l(\gamma) < l(\upsilon \circ \eta) = l(\upsilon)$, from which we get $\pi < 4$.