Martin vB's answer not only gets $d = \frac{3}{49}$ instead of $d = \frac{3}{7}$ but doesn't even work, AFAICT. Here's his pattern drawn out:
..............
......W......W
.....W......W.
....W......W..
..B......B....
.B......B.....
B......B......
..............
......W......W
.....W.!....W.
....W...!..W..
..B......B....
.B......B.....
B......B......
The !
s indicate where a black queen threatens a white queen in this pattern.
However, observing that we need an extra column, not an extra row, we could use the same general principle to come up with something like this that does work:
....W.W.....W.W.
.....W.......W..
....W.W.....W.W.
B.B.....B.B.....
.B.......B......
B.B.....B.B.....
....W.W.....W.W.
.....W.......W..
....W.W.....W.W.
B.B.....B.B.....
.B.......B......
B.B.....B.B.....
The density here is a paltry $\frac{5}{48} \approx 0.104$, so it's not as good as your original
B...B...B...B...
..W...W...W...W.
B...B...B...B...
..W...W...W...W.
B...B...B...B...
..W...W...W...W.
which has a density of $\frac{6}{48} = 0.125$.
If you permit solutions that aren't "the same density everywhere", you can also get $d = 0.125$ with something like
B...............
BB..............
BBB.............
BBBB............
BBBBB...........
BBBBBB..........
BBBBBBB.........
........WWWWWWWW
.........WWWWWWW
..........WWWWWW
...........WWWWW
............WWWW
.............WWW
..............WW
...............W
(drawn out to infinity in each direction, so that one-eighth of the plane is all black and the opposite eighth is all white). I don't think you can do better than $d = \frac{1}{8} = 0.125$ by this variation, though.
If you are willing to redraw the pattern as the square gets bigger, tending to a continuous solution in the unit square, you can achieve at least $d = \frac{7}{48} \approx 0.1458$. Here's an example solution that gives you exactly $d = \frac{7}{48}$ on a 12x12 grid — but it does not tile, so there's no way to fill the plane with it.
...WW......W
...WW.....WW
...WW....WWW
...W.....WWW
.........WWW
.........WW.
.BB.........
BBB.........
BBB.....B...
BB.....BB...
B.....BBB...
.....BBBB...