Rephrase the problem as:
$$ \sin( \pi/2 + \sin(\pi/2 + \sin(\pi/2 + \sin(\pi/2 + x) ) ) ) = \sin(\sin(\sin(\sin(x))))$$
Our strategy will be to assume the expression above is true for some $x$, "invert" the sine on both sides, and show that the resulting expression cannot possibly have a solution. Doing this process once, we have
\begin{align}
\pi/2 + \sin(\pi/2 + \sin(\pi/2 + \sin(\pi/2 + x) ) ) & = \sin(\sin(\sin(x))) + 2\pi n \\
\textrm{or} & \\
\pi/2 + \sin(\pi/2 + \sin(\pi/2 + \sin(\pi/2 + x) ) ) & = \pi - \sin(\sin(\sin(x))) + 2\pi n
\end{align}
for some integer $n$, which implies
$$ \sin(\pi/2 + \sin(\pi/2 + \sin(\pi/2 + x) ) ) = \pm (\sin(\sin(\sin(x))) + 2 \pi (n - 1/4)),$$
where the $\pm$ covers the two cases above, and indicate that at least one of the two possibilities must hold, but not necessarily both. We must have $n = 0$ since both sine terms must have values in $[-1,1]$. So
$$ \sin(\pi/2 + \sin(\pi/2 + \sin(\pi/2 + x) ) ) = \pm (\sin(\sin(\sin(x))) - \pi/2),$$
and so it must be that both sides of the above expression lie in either the interval $[-1, 1 - \pi/2]$ or the interval $[-1 + \pi/2, 1]$. Applying our strategy once more, we have
$$\sin(\pi/2 + \sin(\pi/2 + x) ) = \pm (\arcsin( \sin(\sin(\sin(x))) - \pi/2) - \pi/2).$$
On the left side, clearly the expression must be in $[-1,1]$, while on the right side, the expression must be either in the interval $[-\pi, \arcsin(1 - \pi/2) - \pi/2]$ or in the interval $[\pi/2 - \arcsin(1 - \pi/2), \pi]$.
We derive a contradiction by showing that neither of these two intervals intersect with $[-1,1]$. In particular, we show that $\arcsin(1 - \pi/2) - \pi/2 < -1$. Using the fact that $\pi > 3$,
$$ \arcsin(1 - \pi/2) - \pi/2 < \arcsin(1 - 3/2) - \pi/2 = -\pi/6 - \pi/2 = - 2\pi/3 < -1.$$