In general, if $X$ is a locally convex topological vector space of uncountable dimension (as a linear space), then the weak$^*$ topology on $X^*$ is not first countable.
Proof. In the weak$^*$ topology a sub-base of the neighborhoods of $0$ is obtained by sets of the form
$$
W_{x,\varepsilon}=\{x^*\in X^*: |x^*(x)|<\varepsilon\}, \quad \varepsilon>0,\, x\in X,
$$
and hence a base is obtained by finite intersections of the above sets. In particular, if ${\mathcal N}$ is a base of the neighbourhoods of $0\in X^*$, then for every $U\in\mathcal N$, there exist $n\in\mathbb N$, $x_1, \ldots x_n\in X$ and $k_1,\ldots k_n\in\mathbb N$, such that
$$
W_{x_1,1/k_1}\cap\cdots\cap W_{x_n,1/k_n}\subset U.
$$
In fact, if each $U$ in $\mathcal N$ is replaced by the intersection $W_{x_1,1/k_1}\cap\cdots\cap W_{x_n,1/k_n}$, then the new collection $\mathcal N'$ of these intersection is still a base of neighbourhoods of $0$.
One step further: The $x_n$'s, can be considered to be linearly independent, for if
$$
x_m=c_1x_1+\cdot+c_kx_k,
$$
then $W_{x_1,1/\ell}\cap\cdots\cap W_{x_k,1/\ell}\subset W_{x_m,1/j}$,
if $\ell>j(|c_1|+\cdots+|c_k|)$.
Now as $\dim X>\aleph_0$ we can find
$y\in X\smallsetminus\mathrm{span}\,\{x_n :n\in\mathbb N\}$. Using Hahn-Banach we can
construct a sequence $\{y_n^*\}_{n\in\mathbb N}\subset X^*$ satisfying
$$
y_n^*(y)=1 \quad\text{and}\quad y^*_n(x_j)=\frac{1}{n},\,\,\text{for $j=1,\ldots,n$.}
$$
Clearly, every open set of the form $W_{x_1,1/k_1}\cap\cdots\cap W_{x_n,1/k_n}$ contains all but finitely many terms of the sequence $\{y_n^*\}_{n\in\mathbb N}$, while $W_{y,1}$ contains none of them. Hence
$$
U\not\subseteq W_{y,1},
$$
for all $U\in\mathcal N$.
