Selfadjointness of Coulomb Hamiltonian in $d\geq3$ dimensions I know that the Coulomb-Hamiltonian $H=-\Delta - |\cdot|^{-1}$ is self-adjoint with $\operatorname{dom}(H)=H^2(\mathbb R^3)$. This follows by the Kato-Rellich-Theorem.
Has the corresponding quadratic form a form domain of $Q(H) = H^1(\mathbb R^3)$?
Is it also true for dimensions which are bigger that $3$? How to see it?
Best wishes :)
 A: The general theorem is XIII.96 in Reed/Simon "Methods of Modern Mathematical Physics, Vol. IV: Analysis of Operators" (Academic Press, 1978). A multiplication operator $V$ is $-\Delta$-bounded with relative bound zero if it is uniformly locally $L^p$ where $p = 2$ if dimension $n \leq 3$ and $p>n/2$ if $n \geq 4$. Then you can apply Kato-Rellich (Th. X.12 in Reed/Simon Vol. II) to get a self-adjoint operator $H = -\Delta + V$ with domain $H^2(\mathbb{R}^n)$ as you state correctly.
For your singular Coulomb potential the $L^p$-condition means the following integral (over a small bounded region around the origin, so we choose a ball $B$ with radius 1) has to converge.
$$ \int_B |V(x)|^p d^n x $$
For $V(x)=-|x|^{-1}$ this is equivalent to
$$ \int_0^1 r^{-p+n-1} dr < \infty. $$
We get the condition $-p+n-1 > -1$ thus $n > p$. So your statement is true in dimensions $n \geq 3$. For potentials bounded from below, you have even more options (i.e. locally $L^2$ for all dimensions), see http://www.math.caltech.edu/papers/bsimon/xliv.pdf, p.3 for an introduction and references.
The idea using quadratic forms could be used to include even more singular potentials. But I would be careful about the domain (you need something like $\sqrt{|V|} \psi \in L^2$ for $\psi \in H^1$) of the quadratic form, maybe you can find some hints in another paper by B. Simon:
http://www.math.caltech.edu/SimonPapers/13.pdf
Enjoy! ;-)
A: This is related to a problem posed by Tosio Kato in 1953 and not resolved until 2002, a few years after Kato's death. Take a look at the references on this page to Kato's Conjecture:
     http://www.math.missouri.edu/~hofmann/

I believe that you are essentially correct because the form domain is related to the square root of the elliptic operator, and that is related to Kato's conjecture.
     http://en.wikipedia.org/wiki/Kato_conjecture

I don't think that the Coulombic singularity is a problem for what you are wanting to say.
