Let $G$ be a lie group and $\mathfrak{g}$ its lie algebra. Consider the category $Rep(G)$ of finite dimensional representations of $G$ and the category $Rep(\mathfrak{g})$ of finite dimensional representations of $\mathfrak{g}$. Morphisms in those categories are just $G$- resp. $\mathfrak{g}$ equivariant linear maps. There is an obvious functor $$d\colon Rep(G)\rightarrow Rep(\mathfrak{g}),\pi\mapsto d_e\pi$$ which maps a representation of $G$ to a representation of $\mathfrak{g}$ by taking the derivative at the neutral element. On morphisms, $d$ is just the identity because $G$ equivariant maps are also $\mathfrak{g}$ equivariant, what can be seen by putting 1-parameter subgroups of $G$ in the defining definition of beeing $G$ equivariant and taking the derivative.
If $G$ is simply connected, $d$ is bijective on objects, because Lie group homomoprhism are in bijection to the morphisms of their lie algebras, if the domain is simply connected.
Is $d$ bijective on morphisms too? So $d$ is an isomorphism of categories?
The question reduces to the question, whether every $\mathfrak{g}$ equivariant linear map between vector spaces is $G$ equivariant.