Probably the most straightforward method (to fully distinguish between the various possibilities) that I've seen is transforming the corresponding augmented matrix into row-reduced echelon form. In this case, you would start with: $$\left[\begin{array}{ccc|c}1 & 3 & -1 & -4\\4 & -1 & 2 & 3\\2 & -1 & -3 & 1\end{array}\right]$$ Subtracting $4$ times the first row from the second, and $2$ times the first row from the third, we have: $$\left[\begin{array}{ccc|c}1 & 3 & -1 & -4\\0 & -13 & 6 & 19\\0 & -7 & -1 & 9\end{array}\right]$$ Subtracting $2$ times the third row from the second, we have: $$\left[\begin{array}{ccc|c}1 & 3 & -1 & -4\\0 & 1 & 8 & 1\\0 & -7 & -1 & 9\end{array}\right]$$ Adding $7$ times the second row to the third, we have: $$\left[\begin{array}{ccc|c}1 & 3 & -1 & -4\\0 & 1 & 12 & 1\\0 & 0 & 55 & 16\end{array}\right]$$
At this point, we have only zeroes below the main diagonal, but no zeroes on the diagonal, so a unique solution exists. Continuing to reduce until the $3\times 3$ portion of the augmented matrix is just the $3\times 3$ identity matrix, we have $$\left[\begin{array}{ccc|c}1 & 0 & 0 & 3/11\\0 & 1 & 0 & -73/55\\0 & 0 & 1 & 16/55\end{array}\right]$$ This tells us that $x=3/11,$ $y=-73/55,$ $z=16/55$ is the unique solution to the system.
Let's consider another system: $$\begin{cases}x+3y-z=4\\4x-y+2z=8\\2x-7y+4z=-3,\end{cases}$$ which has corresponding matrix $$\left[\begin{array}{ccc|c}1 & 3 & -1 & 4\\4 & -1 & 2 & 8\\2 & -7 & 4 & -3\end{array}\right].$$ Starting out the same way gets us $$\left[\begin{array}{ccc|c}1 & 3 & -1 & 4\\0 & -13 & 6 & -8\\0 & -13 & 6 & -11\end{array}\right],$$ and subtracting the second row from the third gives us $$\left[\begin{array}{ccc|c}1 & 3 & -1 & 4\\0 & -13 & 6 & -8\\0 & 0 & 0 & -3\end{array}\right].$$ Now we have only zeroes below the main diagonal, but we have a zero on the main diagonal, too. This tells us that either there are no solutions or there are infinitely-many. Translated back into terms of $x,y,z$ this is the equivalent system $$\begin{cases}x+3y+-z=4\\0x-13y+6z=-8\\0x+0y+0z=-3,\end{cases}$$ or alternatively $$\begin{cases}x=-\frac5{13}z+\frac{28}{13}\\y=\frac6{13}z+\frac8{13}\\0=3,\end{cases}$$ but there is no solution to the last equation, so no solution to the system.
Upshot: We will have no solutions whenever we end up with one or more rows of all $0$s except in the last column as we reduce the augmented matrix.
By contrast, if we'd started with the system $$\begin{cases}x+3y-z=4\\4x-y+2z=8\\2x-7y+4z=0,\end{cases}$$ which has corresponding matrix $$\left[\begin{array}{ccc|c}1 & 3 & -1 & 4\\4 & -1 & 2 & 8\\2 & -7 & 4 & 0\end{array}\right],$$ then our reduction process will get us $$\left[\begin{array}{ccc|c}1 & 3 & -1 & 4\\0 & -13 & 6 & -8\\0 & 0 & 0 & 0\end{array}\right].$$ Again, we must have no solution or infinitely many. Continuing to row-reduce as much as possible gets us to $$\left[\begin{array}{ccc|c}1 & 0 & 5/13 & 28/13\\0 & 1 & -6/13 & 8/13\\0 & 0 & 0 & 0\end{array}\right].$$ Translated back into terms of $x,y,z$ this is the equivalent system $$\begin{cases}x+0y+\frac5{13}z=\frac{28}{13}\\0x+y-\frac6{13}z=\frac8{13}\\0=0.\end{cases}$$ One of these equations is always true, so one of our variables can take on any value. We might as well let $z$ take on any value, at which point the other two equations will tell us the values that $x$ and $y$ must take. Hence, we have infinitely-many solutions.
Upshot: We will have infinitely-many solutions whenever we end up with one or more rows of all $0$s as we reduce the augmented matrix, so long as we don't have any rows with all $0$s except in the last column.
Added: Simply taking the determinant of the unaugmented matrix of the system--meaning of $$\begin{bmatrix}1 & 3 & -1\\4 & -1 & 2\\2 & -1 & -3\end{bmatrix}$$ in the first example and of $$\begin{bmatrix}1 & 3 & -1\\4 & -1 & 2\\2 & -7 & 4\end{bmatrix}$$ in the other two examples--will give us part of the answer. If the determinant is $0$ (as in the second and third example), then the system either has no solution or infinitely-many, but we cannot (by this method alone) say which. Otherwise, the system has a unique solution, but we cannot (by this method alone) say what it might be. That's why I tend to prefer the first method I suggested, at least when dealing with only a few equations and a few variables: it tells us the whole story.