This is essentially contained in youler's answer to Diffeomorphism of $\mathbb{C}P^1$ and $S^2$.
$S^2$ has a smooth atlas consisting of the stereographic projections
$$\varphi_1 : S^2 \setminus \{N\} \to \mathbb C = \mathbb R^2, \varphi_1(z,\alpha) = \frac{z}{1-\alpha}, $$
$$\varphi_2 : S^2 \setminus \{S\} \to \mathbb C, \varphi_2(z,\alpha) = \frac{z}{1+\alpha}. $$
Concerning the stereorgraphic projection see for example Two equal smooth structures on $S^n$.
$\mathbb{CP}^1$ has a smooth atlas consisting of the maps
$$\psi_1 : \mathbb{CP}^1 \setminus \{[0:1]\} \to \mathbb C,\psi_2[z:w]=w/z ,$$
$$\psi_2 : \mathbb{CP}^1 \setminus \{[1:0]\} \to \mathbb C, \psi_2[z:w]=\overline{z/w}.$$
The inverses of the $\psi_i$ are
$$\psi_1^{-1}(\omega) = [1:\omega], $$
$$\psi_2^{-1}(\zeta) = [\overline \zeta:1]. $$
This gives diffeomorphisms
$$\delta_1 = \psi_1^{-1} \circ \varphi_1 :S^2 \setminus \{N\} \to \mathbb{CP}^1 \setminus \{[0:1]\} ,$$
$$\delta_2 = \psi_2^{-1} \circ \varphi_2 :S^2 \setminus \{S\} \to \mathbb{CP}^1 \setminus \{[1:0]\} .$$
youler showed that they fit together to a diffeomorphism
$$\Delta : S^2 \to \mathbb{CP}^1 $$
such that $\Delta(N) = [0:1]$ and $\Delta(S) = [1:0]$.
Thus $\delta_1$ is the restriction of the diffeomorphism $\Delta$. In other words, $\delta_1$ extends to a diffeomorphism via $N \mapsto [0:1]$. We have
$$\delta_1(z,\alpha) = \left[1 : \frac{z}{1-\alpha}\right] = [1-\alpha : z] .$$
This is not exactly the map $\varphi$ in your question. However, the map $\tau : \mathbb{CP}^1 \to \mathbb{CP}^1, \tau[z:w] = [2w:z]$, is easily seen to be a diffeomorphism such that $\tau[1:0] = [0:1]$ and $\tau[0:1] = [1:0]$ (use the above charts $\psi_i$ to see that the maps $\tau$ and $\tau^{1}[w:z] = [z:w/2]$ are smooth).
This proves the claim in your question.