I think the answer depends on the way you toss the „coin“.
Let’s regard the coin as a body of rotation around the $y$-axis generated by a rectangle with the vertices $(\pm r, \pm h/2)$ and say we toss it so it rotates randomly around the $z$-axis. When the coin hits the floor, physics tells us, that to see on which side it falls, we have to drop the perpendicular from the mass centre. If it points into the direction of one of the faces, the coin will fall on that face and if it points in the direction of the side, the coin will fall on the side.
Now we assume that the angle of rotation and so also the direction of the dropped perpendicular, at the point of impact, is uniformly distributed over $[0, 2π]$. In the $x$-$y$-projection denote the angle $(b/2, -a/2), (0, 0), (r, h/2)$ as $α$ and the angle $(-r, h/2), (0, 0), (r, h/2)$ as $β$ (so that $α+β=π$). Now if top, bottom and the side of the coin should have the same probability, under the above assumption $2α$ (the angle range for outcome ‚side‘) must be equal to $β$ (the angle range for outcome ‚top‘ as well as for ‚bottom‘). Thus $$α+β = 3α = π ⇒ α = \frac13π, β = \frac23π\\\frac{2r}{h} = \frac{\sin (β/2)}{\sin (α/2)} = \sqrt{3}$$