Let $$
A(n)= \prod_{i=1}^{n}S(2i-1), \qquad B(n)= \prod_{i=1}^{n}S(2i)
$$
Suppose we have shown $A(n)\geq B(n)$ for all values of $n\geq 5$ up to $5k-1$. We will show that $A(n)\geq B(n)$ holds for all values of $n$ up to $5(k+1)-1$. Thus after checking values of $n$ up to 9, we are done by induction on $k$.
Clearly $2(5k)=10k$ has $0$ as its last digit. Thus $2(5k+i)$ for $i=0,1,2,3,4$ will all have identical digits except for the last one, and $B(5k+4)/B(5k-1)$ is the product of $$x,x+2,x+3,x+4,x+6, x+8,\qquad (1)$$
where $x=S(10k)$. Let $y=S(10k-1)$. Then $A(5k+4)/A(5k-1)$ is the product of $$y,x+1,x+3,x+5,x+7. \qquad (2)$$
Note that the last four terms listed in $(1)$ are larger than their counterparts in $(2)$. Thus if the inequality failed for any value of $n$ in the range $5k,5k+1,5k+2,5k+3,5k+4$, then it would fail for $n=5k+4$.
Next note that $y\geq x+8$, as adding $1$ to $10k-1$ will result in at least one digit $9$ being replaced by a digit $0$, and the only other change to the digits is one of them being increased by $1$.
Thus we have $$y\geq x+8, \qquad x+1>x,\qquad x+3>x+2,$$ $$x+5>x+4,\qquad x+7>x+6,$$
so the product of the terms in $(2)$ is greater than the product of the terms in $(1)$.