Let $$f(k,r) \doteq \sum_{j=0}^{k-1} \sin^{2r}\frac{(2j+1)\pi}{2k+1}.$$ We show that $$f(k,r) = \frac{2k+1}{2^{2r+1}} \binom{2r}{r}$$ for positive integers $k$ and $r$. In particular, this yields the requested result $f(3,2) = 21/16$.
Substituting $\sin \theta = (e^{i\theta}-e^{-i\theta})/(2i)$, we write $f(k,r)$ as $$f(k,r) = f(\omega,k,r) \quad\text{with}\quad \omega \doteq \exp\left(\frac{2 \pi i}{2k+1}\right),$$ where $$f(x,k,r) \doteq \frac{1}{(2i)^{2r}}\sum_{j=0}^{k-1} \left(x^{2j+1}-x^{-(2j+1)}\right)^{2r}.$$ A binomial expansion yields $$f(x,k,r) = \frac{1}{(-4)^r}\sum_{a=0}^{2r}{(-1)^a \binom{2r}{a}\sum_{j=0}^{k-1} x^{2(2j+1)(a-r)}}.$$ We break the sum up into terms $a < r$, $a > r$, and $a = r$ to write this as $$f(x,k,r) = g(x,k,r) + g(x^{-1},k,r) + \frac{k}{4^r}\binom{2r}{r},$$ where $$g(x,k,r) \doteq \frac{1}{4^r}\sum_{a=0}^{r-1}{(-1)^{a-r} \binom{2r}{a}\sum_{j=0}^{k-1} \left(x^{2(a-r)}\right)^{2j+1}}.$$ Evaluating the geometric sum yields $$g(x,k,r) = \frac{1}{4^r}\sum_{a=0}^{r-1}{(-1)^{a-r} \binom{2r}{a} \frac{x^{2(2k+1)(a-r)}-x^{2(a-r)}}{x^{4(a-r)}-1}}.$$ For the special case $x = \omega$, the fact that $\omega^{2k+1}=1$ implies $$g(\omega,k,r) = -\frac{1}{4^r}\sum_{a=0}^{r-1}{(-1)^{a-r} \binom{2r}{a} \frac{1}{\omega^{2(a-r)}+1}}.$$ The identity $1/(z+1) + 1/(z^{-1}+1) = 1$ yields the further simplification $$f(\omega,k,r) =\frac{k}{4^r}\binom{2r}{r} - \frac{1}{4^r}\sum_{a=0}^{r-1}{(-1)^{a-r} \binom{2r}{a}}.$$ Finally, expanding $(1-1)^{2r}$ with the binomial theorem simplifies the second term above and we arrive at the result $$f(k,r) = \frac{2k+1}{2^{2r+1}} \binom{2r}{r}.$$