Let $$\sum_{i=1}^{n}{\frac{1}{x_i}}+\frac{n(n-2)}{\sum\limits_{i=1}^{n}{x_i}}<(n-1)(n-2)$$ for some values of $x_i$, $x_i=ka_i,$ where $k>0$ and
$$\sum_{i=1}^{n}{\frac{1}{a_i}}+\frac{n(n-2)}{\sum\limits_{i=1}^{n}{a_i}}=(n-1)(n-2).$$
Thus, $$\frac{1}{k}(n-1)(n-2)<(n-1)(n-2),$$ which gives $k>1$ and we obtain:
$$n-2=\sum_{i=1}^{n}{\frac{1}{x_i+1}}=\sum_{k=1}^{n}{\frac{1}{ka_i+1}}<\sum_{k=1}^{n}{\frac{1}{a_k+1}},$$ which is a contradiction because we'll prove now that $$\sum_{k=1}^{n}{\frac{1}{a_k+1}}\leq n-2$$ for any positives $a_i$ such that $$\sum_{i=1}^{n}{\frac{1}{a_i}}+\frac{n(n-2)}{\sum\limits_{i=1}^{n}{a_i}}=(n-1)(n-2).$$
Indeed, let $f(x)=\frac{1}{1+x}$ and $g(x)=f'\left(\frac{1}{\sqrt{x}}\right)=-\frac{x}{(1+\sqrt{x})^2}.$
Thus,
$$g''(x)=\frac{3}{2\sqrt{x}(1+\sqrt{x})^4}>0,$$ which says that $g$ is a strictly convex on $(0,+\infty).$
Now, let $\sum\limits_{i=1}^na_i=constant$.
Thus, $\sum\limits_{i=1}^n\frac{1}{a_i}=constant$ and by the Vasc's EV Method Corollary 1.6 it's enough to prove that $\sum\limits_{i=1}^nf(a_i)\leq n-2$
for equality case of $n-1$ variables.
Id est, it's enough to prove that:
$$\frac{n-1}{x+1}+\frac{1}{y+1}\leq n-2,$$ where $x$ and $y$ are positives such that
$$\frac{n-1}{x}+\frac{1}{y}+\frac{n(n-2)}{(n-1)x+y}=(n-1)(n-2)$$ or
$$\frac{n-1}{x+\frac{(n-1)(n-2)}{\frac{n-1}{x}+\frac{1}{y}+\frac{n(n-2)}{(n-1)x+y}}}+\frac{1}{y+\frac{(n-1)(n-2)}{\frac{n-1}{x}+\frac{1}{y}+\frac{n(n-2)}{(n-1)x+y}}}\leq\frac{(n-2)\left(\frac{n-1}{x}+\frac{1}{y}+\frac{n(n-2)}{(n-1)x+y}\right)}{(n-1)(n-2)}$$ or
$$(x-y)^2x(2nxy+(x-y)^2)\geq0$$ and we are done!