To simplify derivation, we will translate
- unit hypercube $\mathcal{C}$ to $\mathcal{C}' = [0,1]^n$.
- plane $V$ to $V' = \left\{ (x_1,\ldots,x_n) \in \mathbb{R}^n : \sum\limits_{i=1}^n x_i = \frac{n}{2} \right\}$.
Before we start, let's adopt some conventions.
- For any $p \in \mathbb{R}^n$, we will use $p_1,\ldots,p_n$ to denote its components. ie. $p = (p_1,p_2,\ldots,p_n)$.
- For any $p, q \in \mathbb{R}^n$, we will use $p \ge q$ as a shorthand for the relation, $p_i \ge q_i$ for all $i = 1,\ldots, n$.
- For any $p\in \mathbb{R}^n$, let $C_p$ be the cone $\{ x \in \mathbb{R}^n : x \ge p \}$.
- Let $\mathcal{V}$ be vertices of $\mathcal{C}'$ and for $v \in \mathcal{V}$, we will use $(-1)^v$ be a shorthand of $(-1)^{\sum_{i=1}^n v_i}$.
- For any $U \subset \mathbb{R}^n$, we will use $\mathbb{1}_U$ to denote its indicator function.
- For any expression $(\cdots)$, we will use $(\cdots)_{+}$ to denote its positive part, ie. $\max((\cdots),0)$.
Let $m \in \mathbb{R}^n$ be an unit vector with all components positive. For any $t \in \mathbb{R}$, let
- $H_t$ be the half-space $\{ x \in \mathbb{R}^n : m \cdot x \le t \}$.
- $P_t$ be the hyperplane $\{ x \in \mathbb{R}^n : m \cdot x = t \}$.
Let $\mathcal{S}$ be the collection of geometric shapes $\mathbb{R}^n$ that can be formed by finite intersection of open/closed half-spaces. For any $S \in \mathcal{S}$, let $\mu_{n}(S)$ and $\mu_{n-1}(S)$ be the $n$ and $n-1$ dimensional measure of $S$ whenever it make sense.
When $S$ is bounded, aside from finitely many $t$ where $P_t$ contains a facet of closure of $S$, the hyper area of its intersection with $P_t$ is related to the hyper volume of its intersection with $H_t$ by the relation:
$$\mu_{n-1}(S \cap P_t) = \frac{d}{dt}\mu_n(S \cap H_t)$$
Let $\mathcal{C}'' = [0,1)^n$, notice its indicator function is related to those of $C_v$ be the relation.
$$\mathbb{1}_{\mathcal{C}''} = \sum_{v \in \mathcal{V}} (-1)^v \mathbb{1}_{C_v}$$
We find
$$\begin{align}
\mu_n(\mathcal{C}' \cap H_t) =\mu_n(\mathcal{C}'' \cap H_t)
&= \sum_{v \in \mathcal{V}} (-1)^v \mu_n( C_v \cap H_t )\\
&= \sum_{v\in \mathcal{V}} (-1)^v \mu_n( C_0 \cap H_{t-m\cdot v} )\\
&= \frac{1}{n!\prod_{i=1}^n m_i}\sum_{v\in \mathcal{V}} (-1)^v (t - m\cdot v)_{+}^n
\end{align}$$
This leads to
$$
\mu_{n-1}(\mathcal{C}' \cap P_t)
= \frac{d}{dt} \mu_n(\mathcal{C}' \cap H_t)
= \frac{1}{(n-1)!\prod_{i=1}^n m_i}\sum_{v\in \mathcal{V}}(-1)^k (t - m\cdot v)_{+}^{n-1}
$$
For the problem at hand, we can take all $m_i = \frac1{\sqrt{n}}$ and $P_{\frac{\sqrt{n}}{2}}$ coincides with hyperplane $V'$. This means,
$${\rm Vol}(\mathcal{C} \cap V) = {\rm Vol}(\mathcal{C}' \cap V')
= \mu_{n-1}(\mathcal{C}' \cap P_{\frac{\sqrt{n}}{2}} )$$
Notice $m\cdot v = \frac{1}{\sqrt{n}}\sum\limits_{i=1}^n v_i$ and for $k = 0,\ldots, n$, there are $\binom{n}{k}$ vertices with $\sum\limits_{i=1}^n v_i = k$. At the end, we find:
$$\begin{align}
{\rm Vol}(\mathcal{C},V)
&= \frac{(\sqrt{n})^n}{(n-1)!}\sum_{k=0}^n (-1)^k \binom{n}{k}\left(\frac{\frac{n}{2} - k}{\sqrt{n}}\right)_{+}^{n-1}\\
&= \frac{\sqrt{n}}{(n-1)!}\sum_{k=0}^{\left\lfloor\frac{n}{2}\right\rfloor} (-1)^k \binom{n}{k}\left(\frac{n}{2} - k\right)^{n-1}\tag{*1}
\end{align}
$$
As a double check, let's look at the special case $n = 3$.
$V$ will be a regular hexagon will side $\frac{1}{\sqrt{2}}$. So its area
will be $\frac{3\sqrt{3}}{2}\left(\frac{1}{\sqrt{2}}\right)^2 = \frac{3\sqrt{3}}{4}$.
For comparison, the formula $(*1)$ reproduces
$\frac{\sqrt{3}}{2!}\left(\left(\frac32\right)^2 - 3\left(\frac12\right)^2\right) = \frac{3\sqrt{3}}{4}$ as expected.