Does $ G_2 $ have an $ A_8 $ subgroup? I think the answer is yes and that moreover this $ A_8 $ subgroup is maximal among the closed subgroups of $ G_2 $.
Some circumstantial evidence is that $ A_8 $ has a degree 7 irrep with Frobenius–Schur indicator 1 so it is a subgroup of $ SO_7 $ and $ G_2 $ is also a subgroup of $ SO_7 $. Also $ A_8 $ has a degree 14 irrep with Frobenius–Schur indicator 1, which could very possibly be the action of $ A_8 $ by the adjoint representation on the Lie algebra of $ G_2 $, which has dimension 14 ( a finite subgroup of a connected Lie group like $ G_2 $ being maximal among the closed subgroups is closely related to acting irreducibly in the adjoint representation).
This is all just conjecture though, I'm not familiar enough with $ G_2 $ to prove any of this. For what it's worth generators for the 7d irrep of $ A_8 $ are given
https://brauer.maths.qmul.ac.uk/Atlas/alt/A8/gap0/A8G1-Zr7B0.g
and generators for the 14d irrep of $ A_8 $ are given
https://brauer.maths.qmul.ac.uk/Atlas/alt/A8/gap0/A8G1-Zr14B0.g
Especially for the $ 7 \times 7 $ generators I would imagine someone out there can "recognize" when matrices are " $ G_2 $ matrices" the same way that one can "check" if a matrix is symplectic.