Let $$\frac{\Sigma_d}{\operatorname{Tr}\Sigma_d} = \mathrm{diag}(a_1, a_2, \cdots, a_d).$$
By Jensen's inequality, we have
$$\mathbb{E}\left[\frac{1}{\|x\|^4}\right]
\ge \frac{1}{(\mathbb{E}[\|x\|^2])^2} = 1. \tag{1}$$
Using the known identity ($q > 0$)
$$\frac{1}{q^2} = \int_0^\infty t\, \mathrm{e}^{-tq} \, \mathrm{d} t,$$
we have
\begin{align*}
\mathbb{E}\left[\frac{1}{\|x\|^4}\right] &= \mathbb{E}\left[ \int_0^\infty t\,\mathrm{e}^{-t\|x\|^2} \,\mathrm{d} t \right]\\
&= \int_0^\infty t\, \mathbb{E}[\mathrm{e}^{-t\|x\|^2}]\, \mathrm{d} t \\
&= \int_0^\infty t\, \prod_{i=1}^d \mathbb{E}[\mathrm{e}^{-tx_i^2}]\, \mathrm{d} t\\
&= \int_0^\infty t\, \prod_{i=1}^d \frac{1}{\sqrt{1 + 2a_i t}} \,\mathrm{d} t \\
&= \int_0^\infty t\, \mathrm{e}^{-\frac12\sum_{i=1}^d \ln (1 + 2a_i t)} \,\mathrm{d} t \tag{2}
\end{align*}
where we use
$\mathbb{E}[\mathrm{e}^{-tx_i^2}] = \int_{-\infty}^\infty \mathrm{e}^{-ty^2}\cdot \frac{1}{\sqrt{2\pi a_i}}\mathrm{e}^{-\frac{y^2}{2a_i}}\,\mathrm{d} y = \frac{1}{\sqrt{1 + 2a_i t}}$.
Fact 1: $\ln(1 + 2a_i t) \ge \frac{1}{i}\ln (1 + 2a_1 t)$ for all $i$ and all $t \ge 0$.
(Proof: Note that $a_i = a_1/i$. Let $f(t) = \ln(1 + 2a_i t) - \frac{1}{i}\ln (1 + 2a_1 t)$. We have $f'(t) = \frac{4a_1^2 t (i - 1)}{i(2a_1t + i)(2a_1 t + 1)} \ge 0$.
Also, $f(0) = 0$. The desired result follows.)
Denote $H_d = \sum_{i=1}^d \frac{1}{i}$. By Fact 1, we have
$$-\frac12\sum_{i=1}^d \ln (1 + 2a_i t)
\le -\frac12 \ln(1 + 2a_1 t) \cdot \sum_{i=1}^d \frac{1}{i}
\le - \frac12 H_d\ln(1 + 2t/H_d). \tag{3}$$
From (3), we have
$$
\int_0^\infty t\, \mathrm{e}^{-\frac12\sum_{i=1}^d \ln (1 + 2a_i t)} \,\mathrm{d} t
\le \int_0^\infty t\, \mathrm{e}^{- \frac12 H_d\ln(1 + 2t/H_d)} \,\mathrm{d} t. \tag{4}
$$
From (1) and (2) and (4), we have
$$1\le \mathbb{E}\left[\frac{1}{\|x\|^4}\right] \le \int_0^\infty t\, \mathrm{e}^{- \frac12 H_d\ln(1 + 2t/H_d)} \,\mathrm{d} t. $$
By the Dominated Convergence Theorem, we have
$$\lim_{d\to \infty} \int_0^\infty t\, \mathrm{e}^{- \frac12 H_d\ln(1 + 2t/H_d)} \,\mathrm{d} t = 1.$$
(Note: Note that $u \mapsto u \ln (1 + 2t/u)$
is non-decreasing on $u > 0$. Let $f_d(t) = t\, \mathrm{e}^{- \frac12 H_d\ln(1 + 2t/H_d)}$. Then $f_2(t) \ge f_3(t) \ge \cdots $, and $\lim_{d\to \infty} f_d(t) = t\mathrm{e}^{-t}$,
and $\int_0^\infty f_m(t)\,\mathrm{d} t < \infty$ for some $m$.
See: Monotone Convergence theorem for decreasing sequence)
Thus, we have
$$\lim_{d\to \infty} \mathbb{E}\left[\frac{1}{\|x\|^4}\right] = 1.$$
We are done.
