Given that here should be interpreted as In the condition that, which is a case of Conditional Probability, quoting Wikipedia:
In probability theory, conditional probability is a measure of the probability of an event occurring, given that another event (by assumption, presumption, assertion or evidence) has already occurred.
We define
- $A$ to be the event that the man receives exactly two tails.
- $B$ to be the event that he gets more than one head.
So the probability of getting at least two heads on 5 flips is
$$
P(B)=1 - \left(\frac 12 \right)^5-\binom{5}{1}\left(\frac 12 \right)^5 = \frac{13}{16}
$$
While getting exactly two tails as well as getting at least two heads is
$$
P(A\cap B) = \binom{5}{2}\left(\frac 12 \right)^5 = \frac{5}{16}
$$
Note: This value is the same as $P(A)$ because having exactly two tails implies that he's got at least two heads (three, actually).
Using the formula for conditional probability, that is,
$$
P(A\mid B) = \frac{P(A\cap B)}{P(B)}
$$
We get,
$$
P(A\mid B) = \frac{\frac{5}{16}}{\frac{13}{16}} = \frac 5{13}
$$
Which is what we wanted.
If $P(A|B) = P(A)$, then $A$ and $B$ must be independent. That is, knowledge about either event does not alter the likelihood of each other. Explained in English: As you already know that there are at least $2$ tails, the probability of it still having $2$ heads is changed relevant to not knowing anything.