First, select the number that appears exactly $3$ times: $6$ ways. We have $\binom{6}{3}$ ways to place them.
Now, in the rest of the $3$ positions, you have $5$ options. So, count = $$6 \cdot \binom{6}{3} \cdot 5^3$$
But, in this we are also counting the number arrangements of $3 + 3$ (so two numbers appear $3$ times), so subtract $$\binom{6}{2} \cdot 2 \cdot \binom{6}{3}$$ This is subtracting the number of ways to pick $2$ numbers and place them in $3 + 3$.
EDIT: My explanation was wrong and thanks to @N.F.Taussig for pointing it out. I will just put their comment that explains where I am wrong:
The factor of $2\binom{6}{2}\binom{6}{3}$ is twice the number of arrangements in which two numbers each appear three times. That is what we want to subtract since those patterns are counted twice among the $\binom{6}{1}\binom{6}{3}5^3$ arrangements in which a number appears three times, and we don't want to count such arrangements at all. However, your wording suggests that the term you are subtracting is the number of arrangements in which two numbers each appear three times, which is not the case.
So, answer = $$\frac{120 \cdot 125 - 40 \cdot 15}{6^6} = 0.31$$
Currently my thoughts are that we have $6$ choices for our favorable event (the triples)
That is correct.
and for the remaining $3$ numbers we have $5×5×4=100$, $4$ because we do not want to include the possibility of having $3$ same numbers two times
You are ordering the combinations later on, but when multiplying $5 × 5 × 4$ like that, you are not just picking the elements but also ordering them, something which you are doing later on. So, this over-counts. Also, it's not $5 × 5 × 4$, What if the first element (when you multiply by $5$) is the count-$3$-element itself?
and to consider all possible arrangements, there are then $\frac{6!}{3!1!1!1!}$ possibilities.
This is true only if the counts look like $6 = 3 + 1 + 1 + 1$ but what if $6 = 3 + 2 + 1$?
Let me know if you have any questions)))