That wikipedia page has a proof of Zariski's lemma, which states that if $A$ is a Jacobson ring (in particular when $A$ is a field) and $B$ is a finitely-generated algebra of $A$, which is a field, then $B$ is a finite extension of $A$ (as a vector space).
In the proof, the following statement is proved:
(*) Let $B\supseteq A$ be integral domains such that $B$ is finitely generated as $A$-algebra. Then there exists a nonzero $a$ in $A$ such that every ring homomorphism $\phi :A\to K$, $K$ an algebraically closed field, with $\phi (a)\neq 0$ extends to $\widetilde {\phi }:B\to K$.
The proof of this statement begins with
If $B$ contains an element that is transcendental over $A$, then it contains a polynomial ring over $A$ to which $φ$ extends (without a requirement on $a$) and so we can assume $B$ is algebraic over $A$ (by Zorn's lemma, say).
I don't understand why is it possible to assume that. Using Zorn's lemma we can find a ring $R$ such that $A\subseteq R\subseteq B$, every element in $R\setminus A$ is trancendental over $A$ and $B$ is algebraic over $R$. However, if we prove the existence of $a\in R$ which satisfies the statement, how can we know that there is an element in $A$ which satisfies it?