I think this is based in a misunderstanding of how we can convert between $E$ and $F$ vector spaces. For concreteness, let's work with $\mathbb{C}$ and $\mathbb{R}$, but you'll see that the same idea works for any field extension.
You're entirely right that, if we have a decomposition of $\mathbb{C}G$ modules $V = U \oplus W$, then we can apply restriction of scalars to get a decomposition of $\mathbb{R}G$ modules $V = U \oplus W$.
But here's the key thing! When we pass from $\mathbb{C}$ vector spaces to $\mathbb{R}$ vector spaces, the dimension doubles. If $V$ used to be $n$-dimensional as a $\mathbb{C}$-space, it's now $2n$-dimensional as an $\mathbb{R}$-space. Why is this important? Let's look at your example:
Given a representation of $C_3 = \langle g \rangle$ where $g \mapsto \begin{pmatrix} 0 & 1 \\ -1 & -1 \end{pmatrix}$ in $\mathsf{GL}_2(\mathbb{C})$, then (as Dylan says in their answer) $V = \mathbb{C}^2$ decomposes as
$$
\mathbb{C}^2 =
\left \langle \begin{pmatrix} \omega \\ 1 \end{pmatrix} \right \rangle
\oplus
\left \langle \begin{pmatrix} \omega^2 \\ 1 \end{pmatrix} \right \rangle
$$
but now, if we apply restriction of scalars, what representations do we see?
$$
\mathbb{R}^4 =
\left \langle
\begin{pmatrix} - \frac{1}{2} \\ \frac{\sqrt{3}}{2} \\ 1 \\ 0 \end{pmatrix}, \
\begin{pmatrix} - \frac{\sqrt{3}}{2} \\ - \frac{1}{2} \\ 0 \\ 1 \end{pmatrix}
\right \rangle
\oplus
\left \langle
\begin{pmatrix} - \frac{1}{2} \\ -\frac{\sqrt{3}}{2} \\ 1 \\ 0 \end{pmatrix}, \
\begin{pmatrix} \frac{\sqrt{3}}{2} \\ - \frac{1}{2} \\ 0 \\ 1 \end{pmatrix}
\right \rangle
$$
here we're using the well known fact that $\omega = -\frac{1}{2} + \frac{\sqrt{3}}{2} i$, and restriction of scalars turns us from a 2D $\mathbb{C}$-vector space into a 4D $\mathbb{R}$-vector space (where $i$ acts in the obvious way).
Now, importantly, this is not the representation $g \mapsto \begin{pmatrix} 0 & 1 \\ -1 & -1 \end{pmatrix}$ in $\mathsf{GL}_2(\mathbb{R})$! Instead, it's a representation $C_3 \to \mathsf{GL}_4(\mathbb{R})$.
Notice your proof tells us that this 4D vector space decomposes, as indeed it does! But you're trying to conclude that the 2D representation $g \mapsto \begin{pmatrix} 0 & 1 \\ -1 & -1 \end{pmatrix}$ in $\mathsf{GL}_2(\mathbb{R})$ decomposes. Of course, these are very different representations!
What is the relationship? And what goes wrong?
Given $V = \mathbb{R}^2$ with this $C_3$ representation, can freely turn it into a $\mathbb{C}$ representation by taking the complexification $V \otimes \mathbb{C}$. But this new space will be a $2$D $\mathbb{C}$-space. In fact, it's exactly the 2D space that we know decomposes from earlier!
The difference is that, when we take the restriction of scalars of $V \otimes \mathbb{C}$, we don't get our old representation back! Again, we find the dimension doubled!
What's the tl;dr, then? If we start with a reducible $\mathbb{C}G$ representation, you're entirely correct that it gives us a reducible $\mathbb{R}G$ representation too -- in fact, your exact proof works.
However, if we're starting with an $\mathbb{R}G$ representation, it probably isn't a $\mathbb{C}G$ representation. We can make it a $\mathbb{C}G$ representation by tensoring with $\mathbb{C}$, but this changes the space (for instance, its dimension). So if $V \otimes \mathbb{C}$ is reducible, that doesn't necessarily tell us anything about reducibility of $V$!
As an aside, we can still ask when knowledge of $V \otimes \mathbb{C}$ can tell us things about $V$ itself. This turns out to be one of the motivating problems in "descent theory", and while this is difficult, it's fairly well understood.
I hope this helps ^_^