Note: This question has been substantially revised, see the edit history for earlier versions.
So far, the only examples of metric spaces which I have seen in topology books are Euclidean $n$-space, subspaces of Euclidean $n$-space, and the discrete space. Obviously, it is not the case that "every metric space of cardinality $\mathfrak c$ is either homeomorphic to a subspace of Euclidean $n$-space or discrete," so I decided to come up with some counterexamples.
I started by sketching what a potential basis set might look like and trying to find a metric to fit it. I made the obvious observation that any metric topologically equivalent to the Euclidean metric on $\Bbb R^2$ generates a basis of open regions bounded by (what I now realize are) Jordan curves. So I tried to think of a metric for which this isn't the case. I noticed that any example I could think of had the property that an open set, the boundary of an open set, or the exterior of an open set would be countable. This leads me to the idea of what I am calling "Jordan spaces" (previously "non-degenerate metric topology"), which I am defining as follows follows:
Let $X$ be a set of cardinality $\mathfrak c$, and $d$ a metric on $X$. The metric space $(X,d)$ is a Jordan space if and only if for every point $x\in X$ and real number $r>0$, the sets $\{y\in X:d(x,y)<r\}$, $\{y\in X:d(x,y)=r\}$, and $\{y\in X:d(x,y)>r\}$
are individually equinumerous with $X$
together form a partition of $X$
(The second criterion is trivial, but important enough to applications that it's worth stating anyway.)
Note that if $d$ is any metric on $\Bbb R^2$ such that the set $\{y\in \Bbb R^2:d(x,y)=r\}$ forms a Jordan curve for any $x\in\Bbb R^2$ and real number $r>0$, then $(\Bbb R^2,d)$ is a Jordan space. This generalizes to $\Bbb R^n$ in the obvious way - in particular, any metric space which is homeomorphic to Euclidean $n$-space is a Jordan space.
Now the question is this: Is every Jordan space homeomorphic to a subspace of Euclidean $n$-space?
My immediate answer is "almost certainly not," and I have some ideas for a proof, but what I would really like is a concrete example.
Additional note: topology is not my native language, please forgive me any mistakes I make and feel free to correct my vocabulary.