What is the motivation for the axioms for Propositional Calculus in Mendelson's "Introduction to Mathematical Logic"? On pp. 26-27 of his Introduction to Mathematical Logic (5th edition), Elliott Mendelson writes:



*If $\mathscr{B}$, $\mathscr{C}$, and $\mathscr{D}$ are wfs of $\mathrm{L}$, then the following are axioms of $\mathrm{L}$:
(A1) $(\mathscr{B} \Rightarrow (\mathscr{C} \Rightarrow \mathscr{B}))$
(A2) $((\mathscr{B} \Rightarrow (\mathscr{C} \Rightarrow \mathscr{D})) \Rightarrow ((\mathscr{B}\Rightarrow\mathscr{C})\Rightarrow(\mathscr{B}\Rightarrow\mathscr{D})))$
(A3) $(((\neg\mathscr{C})\Rightarrow(\neg\mathscr{B}))\Rightarrow(((\neg\mathscr{C})\Rightarrow\mathscr{B})\Rightarrow \mathscr{C}))$

In my prior experience, axioms have always been chosen so as to closely mirror our intuitions.  E.g. "things that are equal to the same thing are also equal to each other."
In contrast, I find the axioms quoted above completely opaque.
I fail to see the purpose of grounding a theory on such opaque statements.  Sure, one can derive "results" from them, but who cares?  In other words, what makes the results derived from axioms A1, A2, and A3 above more worthy of our interest than results derived from some other random set of equally obscure axioms?

EDIT: Thank you for all the answers and comments!  They have indeed been extremely instructive.  I now have a better idea of what is tripping me up.  It all boils down to the conflict I perceive between the word "axiom", as I have come to understand it from my prior experience (e.g. with Euclid's axioms or Peano's axioms), and Mendelson's A1, A2, and A3.
More specifically, the "axioms" that Mendelson proposes lack two "defining features" of my prior understanding of the word "axiom."
The first of these is that axioms are supposed to codify "plain common sense."  No special training is required to accept them as true.
The second defining feature of my prior idea of an "axiom" is that it cannot be justified by appeal to even more obviously true facts.  An "axiom" is not only obviously true, but also irreducibly so.
After reading your comments and answers, I think that I can come up with a reasonable explanation for the first discrepancy.  It goes something like this: in this field the word "axiom" is chosen only (or primarily) for its connotation as "starting point".  All other traditional connotations of the word "axiom" (such as "being commonsensical") are left out.  In this new usage, "axiom" is, basically, a "term of art".  It is suggestive, in the same way that words like "expression," "clause," and "statement" are when used to describe a computer "language".  The meanings of all these technical words have only a distant resemblance to those of their natural language namesakes.
I have a harder time disposing of the second issue.  What still confuses me is that, in discussions of these axioms, I often come across appeals to using truth tables as a way to convince oneself that these axioms are true.  This suggests to me that these "axioms" may be true, but they are certainly not fundamental, since we are justifying them by appeal to something else, namely whatever we appeal to when we use truth tables.  More specifically, it appears as though the real axioms here (in the sense of "rock-bottom principles") are the truth tables for $\neg$ and $\Rightarrow$.
 A: Hilbert himself cites the relevant axioms as follows (see his The Foundations of Mathematics in From Frege to Gödel: A Source Book in Mathematical Logic, 1879-1931 edited by Jean van Heijenoort, Harvard University Press, 1967; I have updated the notation for several symbols):

I. Axioms of implication

*

*$A\to (B\rightarrow A)$ (introduction of an assumption)


*$(A\rightarrow (A\rightarrow B))\rightarrow (A\rightarrow B)$ (omission of an assumption)


*$(A\rightarrow (B\rightarrow C))\rightarrow (B\rightarrow (A\rightarrow C))$ (interchange of assumptions)


*$(B\rightarrow C)\rightarrow ((A\rightarrow B)\rightarrow (A\rightarrow C))$ (elimination of a proposition).
II. Axioms about $\wedge$ and $\vee$


*$A\wedge B\rightarrow A$;


*$A\wedge B\rightarrow B$;


*$A \rightarrow (B \rightarrow A \wedge B)$


*$A\rightarrow A\vee B$;


*$B\rightarrow A\vee B$;


*$((A\rightarrow C)\wedge (B\rightarrow C))\rightarrow ((A\vee B)\rightarrow C))$.
III. Axioms of negation


*$(A\rightarrow B\wedge\neg B)\rightarrow\neg A$ (principle of contradiction);


*$\neg(\neg A))\rightarrow A$ (principle of double negation).
The axioms of groups I, II, and III are nothing but the axioms of the
propositional calculus. From 11 and 12 there follows, in particular,
the formula
$(A\wedge\neg (A))\rightarrow B$
and further the logical principle of excluded middle,
$((A\rightarrow B)\wedge (\neg A\rightarrow B))\rightarrow B$.

We are more interested in the implicational fragment. The names of the axioms Hilbert supplies a guidance. The first axiom, for instance, can be further explicated as: We have already a proposition $A$, and if we assume $B$, then we can write $B\to A$, and so for the others.
Looking from the perspective of natural deduction may help grasp the ideas. Dosen gives the following correspondences (see his A Historical Introduction to Substructural Logics in Substuctural Logics edited by Peter Schroder-Heister and Kosta Dosen, Clarendon Press, 1993):
The 1st axiom, introduction of an assumption, corresponds to thinning.
The 2nd axiom, omission of an assumption, corresponds to contraction.
The 3rd axiom, interchange of assumptions, corresponds to permutation.
The 4th axiom, elimination of a proposition, corresponds to what Dosen calls association and notes that it is related to cut rule, which I think more explicative.
The basis that Hilbert set out has been later rearranged into handier systems; Mendelson's is just one of them.
A: I always think of the first axiom as a kind of Conditionalization:
$P$
$\therefore Q \to P$
Conditionalization allows you, in effect, to bring results inside a certain context. That is, once we know that $P$ is true, then within the context of $Q$, we still have $P$.
Now, instead of as an inference, we write this as a single statement $P \to (Q \to P)$, but note that together with the Modus Ponens (MP) inference rule that almost all these kinds of axiom systems have, you can of course now make exactly the above inference:
$P$
$P \to (Q \to P)$ (axiom)
$\therefore Q \to P$ (MP)
The second axiom is a kind of Conditionalized Modus Ponens. In effect, it points out that we can still do Modus Ponens inside a certain context ($P$). That is, the Conditionalized version of Modus Ponens:
$Q \to R$
$Q$
$\therefore R$
becomes:
$P \to (Q \to R)$
$P \to Q$
$\therefore P \to R$
And again, we can capture this with a single statement: $((P \to (Q \to R) \land (P \to Q)) \to (P \to R)$ which by Exportation is equivalent to:
$((P \to (Q \to R) \to ((P \to Q) \to (P \to R))$
(and you really want the latter, since you want to express everything with $\to$'s and $\neg$'s)
Because of these two properties, we can prove the Deduction Theorem as a result of these two axioms:
If $\Gamma, \phi \vdash \psi$, then $\Gamma \vdash \phi \to \psi$
That is:  If we can derive $\psi$ from $\Gamma$ within the further context of $\phi$, then we can derive the conditionalized version of $\psi$, i.e. $\phi \to \psi$ from $\Gamma$ alone.
This important meta-logical result is why you so often see these first two axioms included in the various axiom systems.
Now, the third axiom is, by itself, probably the most understandable one: it expresses the Reductio Ad Absurdum: we can prove $P$, if we can show that its opposite $\neg P$ leads to a contradiction (i.e. if $\neg P$ leads to both $Q$ and $\neg Q$ for some statement $Q$:
$\neg P \to Q$
$\neg P \to \neg Q$
$\therefore P$
And once again, we can capture this with a single statement (reversing the two premises): $((\neg P \to \neg Q) \land (\neg P \to Q)) \to P$ which (again by Exportation) is equivalent to:
$(\neg P \to \neg Q) \to ((\neg P \to Q) \to P)$
Now, what's cool about this is that together, these three axioms actually become a complete system, as I am sure other Answers will point out. But I thought I would try to provide you with a more conceptual understanding of the axioms themselves, which is I believe you were really asking for.
A: Note: This answer works with $\neg,\to$ as the base connectives, the word "calculus" always refers to a Hilbert-style proof calculus for propositional logic.The system presented in Mendelson is a sound and complete Hilbert-style propositional calculus. It’s easy to check that all the axioms are logical validities, and since modus ponens is a valid inference rule, one has the following theorem:Soundness:Given a set of assumptions $T$, if there is a proof of $\phi$ from $T$, then $T$ semantically entails $\phi$.One obviously wants this theorem to be true, and so can’t pick any random set of axioms, still one could just pick any set of tautologies, this is where completeness comes in, one also wants the calculus to satisfy: Completeness: If $T$ semantically entails $\phi$, then there should be a proof of $\phi$ from $T$ Now if we want both of these to be true we can’t take any random set of even tautologies as axioms, but one may still want take the set of all tautologies instead of the seemingly opaque axiom schemas, but as it turns  out(take a look at the proof of completeness), that one actually requires much less, and if you work very hard and keep trying to remove redundancies, you can come up with a similar set of schemas.(Which is much nicer than throwing in every tautology!)
A: You refer to the axioms as as "opaque" and "obscure", but they are not that at all, once you get used to logic.
For example, $P \Rightarrow (Q \Rightarrow P)$ is trying to say "If $P$ is true, then no matter what $Q$ is, it will imply it".  This tells you the nature of $\Rightarrow$.  If $P$ is true, then $Q \Rightarrow P$ is always true.  You can also think about this as functions.  If I know that $P$ is a non-empty set, with element $a \in P$, then I can define a function from any other set $Q$ by $f(x) = a$.
The next says that if $P \Rightarrow (Q \Rightarrow R)$, then $P \Rightarrow Q$ will imply that $P \Rightarrow R$.  So, if $P$ is enough to prove that $Q$ will imply $R$, and if $P$ implies $Q$ is true, then we must have $R$ based only on the fact $P$ is true.  The function analogy works again.  The assumption is every element $x \in P$ gives us a function $f_x : Q \to R$. Then, from a function $g: P \to Q$, we get a function $P \to R$ by $a \mapsto f_a(g(a))$.
Why one cares, is that we need to make sure the foundations of our mathematical system produces what we want to consider "math", and that it matches our intuition for what rules of logic we use when producing proofs.  For most mathematicians this is "birds don't need to know aerodynamics to fly".  But, someone has to keep track of the foundational theory to make sure it works correctly.
A: 
In other words, what makes the results derived from axioms A1, A2, and A3 above more worthy of our interest than results derived from some other random set of equally obscure axioms?

The results derived from some other sound and complete set of axioms for classical propositional calculus aren't, ceteris paribus, any more or less worthy of our interest than results derived from A1, A2, and A3.  However, getting those results won't be as easy in every single system that could get used (there is no end to such possible systems).  Take a look at the exercises in Mendelsohn's book and see how many of the other systems you find easier to use.

Sure, one can derive "results" from them, but who cares?

Among other things, such axiomatic systems have gotten used to test and help develop theorem provers.  Studying such systems has lead to the development of proof strategies in automated reasoning, which has had applications elsewhere.  The above axiom set, I would argue, also makes it easier to automatically produce tautologies than many, many other and indeed most, other existing and known axiom sets.  I think people who have studied other axiom sets would also tend to agree that the above system comes as easier to use than most other axiom sets in the literature.  Why is that?
As Bram has pointed out (A1) and (A2) allow us to prove a deduction metahtheorem.  The proof for this system is also simpler than the proof for some other systems.  Also, as Bram has pointed out (A3) captures reductio ad abusurdum, and the combination of the two makes reasoning in propositional calculus relatively easy.
In other words, the above system is a relatively easy system in comparison to some others for deriving results, at least in my experience.  Now that does still leave some open questions though...
What's the motivation for using A2: ((B⇒(C⇒D))⇒((B⇒C)⇒(B⇒D))) instead of A2': ((B⇒C)⇒((B⇒(C⇒D))⇒(B⇒D)))?  A2 expresses the principle that '⇒' distributes over itself in one direction, while A2' does not.  Also, Frege used something close to A2.  So, using A2 might get used, in part, because of historical reasons.
What's the motivation for using A3: (((¬C)⇒(¬B))⇒(((¬C)⇒B)⇒C)) instead of A3': (((¬C)⇒B)⇒(((¬C)⇒(¬B))⇒C))?  A3 allows for a short derivation of the law of Clavius: (((¬C)⇒C)⇒C), while the derivation using A3' as an axiom instead would be longer and take some more work.
A: Forgive me to write the Axioms in the ways I am used to:
A1. $\phi \to (\psi \to \phi)$
A2. $(\phi \to (\psi \to \chi)) \to ((\phi \to \psi) \to (\phi \to \chi))$
A3. $(\neg \phi \to \psi) \to ((\neg \phi \to \neg \psi) \to \phi)$
We now use deduction theorem to rewrite the Axioms to help us think.
A1. $\phi \vdash (\psi \to \phi)$
If we have $\phi$, we could add any premise $\psi$ to $\phi$.
A2. $\phi \to (\psi \to \chi), \phi \to \psi \vdash (\phi \to \chi)$
It is actually a strong version of hypothetical syllogism. $\psi \to \chi$ is the premise of $\phi \to (\psi \to \chi)$ and the version using premise $\psi \to \chi$ instead of the consequence $\phi \to (\psi \to \chi)$ is the hypothetical syllogism we always see.
HS. $\psi \to \chi, \phi \to \psi \vdash (\phi \to \chi)$
A3. $\neg \phi \to \psi, \neg \phi \to \neg \psi \vdash \phi$
It is the contradiction. If in the condition of $\neg \phi$ we could infer both $\neg \psi$ and $\psi$, then the contradiction would lead us to $\phi$.
Both A2 and A3 are already in their strongest statement which means that both inverses of these 2 Axioms also hold. It also amazes me that only these 3 Axioms could form a complete system.
