Let $$f_n(\epsilon)=(2n+1)e^{-n(n+1)\epsilon},\qquad Z_\text{odd}(\epsilon)=\sum_{p\ge0}f_{2p+1}(\epsilon),\qquad Z_\text{even}(\epsilon)=\sum_{p\ge0}f_{2p}(\epsilon).$$ (These functions are relevant to describing rotation of diatomic molecules in statistical physics.)
When $\epsilon\searrow0$, these functions are extremly close in value; numerically: $$Z_\text{even}(0.1)-Z_\text{odd}(0.1)\simeq 3\,10^{-9},\qquad Z_\text{even}(0.05)-Z_\text{odd}(0.05)\simeq 2\,10^{-19}.$$ Is there a reason for this? What is an asymptotic equivalent of the difference?
I tried to obtain a small $\epsilon$ expansion using the Euler-MacLaurin expansion and Mathematica, and I found that they both have the same expansion. Notice that Euler-MacLaurin involves derivatives of $f$ at 0 for $Z_\text{odd}$ and derivatives of $f$ at 1 for $Z_\text{even}$, so it is not obvious how this should lead to the same expansion.
[Paragraph added in an edit] In fact, to compare the expansions, it is easier to write $Z_\text{even}(\epsilon)-Z_\text{odd}(\epsilon)=2Z_\text{even}(\epsilon)-Z_\text{total}(\epsilon)$, where $Z_\text{total}(\epsilon)=\sum_{n\ge0} f_n(\epsilon)$. Then, applying Euler-MacLaurin to order $m$ to $Z_\text{even}$ and $Z_\text{total}$, one obtains $$Z_\text{even}(\epsilon)-Z_\text{odd}(\epsilon)=\frac{f_0(\epsilon)}2+\sum_{p=0}^m \frac{b_{2p}(2^{2p}-1)}{(2p)!}f^{(2p-1)}(\epsilon)+R_m(\epsilon).$$ The first terms in this summation are $\frac12$, $\frac14(-2+\epsilon)$, $\frac1{48}(-12\epsilon+12\epsilon^2-\epsilon^3)$, $\frac1{480}(-120\epsilon^2+180\epsilon^3-30\epsilon^4+\epsilon^5)$, $\frac{17}{80\,640}(-1680 \epsilon ^3+3360 \epsilon ^4-840 \epsilon ^5+56 \epsilon ^6-\epsilon ^7)$. Notice how each new term cancels the lowest power of $\epsilon$ remaining. Finally, the result is the remainder term $R_m(\epsilon)$ plus a polynomial of $\epsilon$ with powers going from $\epsilon^{m+1}$ to $\epsilon^{2m+1}$. I find it quite fascinating, but maybe the Euler-MacLaurin approach is not the good one here. [End of paragraph added in the edit]
A last remark: this result is not universal. If I pick the not-so-different function $\tilde f_n(\epsilon)=2n e^{-n^2\epsilon}$, then the corresponding $\tilde Z_\text{odd}$ and $\tilde Z_\text{even}$ differ by a quantity of order $\epsilon$.
So, what is so special about my choice of $f_n(\epsilon)$ ? Why are my two $Z$ functions so close? How can I compute the asymptotic equivalent of $Z_\text{even}(\epsilon)-Z_\text{odd}(\epsilon)$ as $\epsilon\searrow0$ ?