Partial Solution
We begin by transforming our integrand slightly:
$$f(a, b) = \int_{0}^{\infty} x \int_{-\infty}^{\infty} \exp\left(\frac{-a t^2+i b t}{3t^2+1}\right) \frac{e^{i x t}}{3t^2+1} \, dt \, dx$$
Let $a \mapsto 3a, b \mapsto \sqrt{3} \,b$ to give:
$$f(3a, \sqrt{3}\,b) = \int_{0}^{\infty} x \int_{-\infty}^{\infty} \exp\left(\frac{-3a t^2+ \sqrt{3}\, i b t}{3t^2+1}\right) \frac{e^{i x t}}{3t^2+1} \, dt \, dx$$
Now perform the substitution $\sqrt{3} \, t = u \implies dt = \frac{1}{\sqrt{3}} du,$ giving us:
$$f(3a, \sqrt{3} \, b) = \frac{1}{\sqrt{3}}\int_{0}^{\infty} x \int_{-\infty}^{\infty} \exp\left(\frac{-a u^2+ \, i b u}{u^2+1}\right) \frac{e^{i x u/\sqrt{3}}}{u^2+1} \, du \, dx$$
Now separate $\exp\left(\frac{-a u^2+ \, i b u}{u^2+1}\right) = e^{-a} \exp\left(\frac{i b u+a}{u^2+1}\right)$ and perform the substitution $x = \sqrt{3} \, v \implies dx = \sqrt{3} \, dv$, giving us:
$$f(3a, \sqrt{3} \, b) = \sqrt{3}\, e^{-a} \int_{0}^{\infty} v \int_{-\infty}^{\infty} \exp\left(\frac{i b u+a}{u^2+1}\right) \frac{e^{i v u}}{u^2+1} \, du \, dv$$
which then the variables can be relabelled with $v \mapsto x$ and $u \mapsto t$.
Consider the following double integral:
$$g(3a, \sqrt{3} \, b) = \sqrt{3} e^{-a} \int_{0}^{\infty} x \int_{-\infty}^{\infty} e^{i x t} e^{a-t^2+i b t} \, dt \, dx$$
$$\int_{-\infty}^{\infty} \ e^{i x t} e^{a-t^2+i b t} \, dt = -\frac{i}{2}\sqrt{\pi}e^{a-\frac{1}{4}(b+x)^2}\text{erfi}\left(\frac{b+2it+x}{2}\right) \Bigg]_{t=-\infty}^{t=\infty} = \sqrt{\pi}e^{a-\frac{1}{4}(b+x)^2}$$
We choose this function to allow us to avoid the order two pole at $t=0$ of $f(3a, \sqrt{3} \, b)$ when the integrals are swapped and we have a factor of $\frac{1}{t^2}$.
$$\implies g(3a, \sqrt{3} \, b) =\sqrt{3 \pi} \int_{0}^{\infty} x \exp \left(-\frac{(b+x)^2}{4}\right) \, dx = -\sqrt{3\pi}\left(b\sqrt{\pi}\,\text{erf}\,\left(\frac{b+x}{2}\right)+2e^{-\frac{1}{4}(b+x)^2}\right)\Bigg]_{x=0}^{x=\infty}$$
$$\implies g(3a, \sqrt{3}\, b) = \sqrt{3\pi} \left(2 e^{-b^2/4} - b \sqrt{\pi} \, \text{erfc} \, \left(\frac{b}{2}\right)\right)$$
We now introduce $g(3a, \sqrt{3} \, b)$ in order to allow the order of integration to be interchanged:
$$f(3a, \sqrt{3} \, b)=\sqrt3e^{-a}\int_{0}^{\infty}x\int_{-\infty}^{\infty}e^{i xt}\left(\frac{e^{\frac{a+i bt}{1+t^2}}}{1+t^2}-e^{a-t^2+i bt}\right)\, dt \, dx+\sqrt{3\pi}\left(2e^{-b^2/4}-b\sqrt{\pi}\, \, \text{erfc} \,\left(\frac{b}{2}\right)\right)$$
Since $\int_{0}^{\infty} x^{s-1} e^{i x t}\, dx = (-i t)^{-s} \Gamma (s) \implies \int_{0}^{\infty} x e^{i x t} \, dx = -\frac{1}{t^2}$:
$$\implies f(3a, \sqrt{3} \, b) = -\sqrt{3} e^{-a} \int_{-\infty}^{\infty} \frac{1}{t^2}\left( \frac{e^{\frac{i b t+a}{1+t^2}}}{1+t^2} -e^{a-t^2+i b t} \right)\, dt +\sqrt{3\pi}\left(2e^{-b^2/4}-b\sqrt{\pi}\, \, \text{erfc} \,\left(\frac{b}{2}\right)\right)$$
Now introduce the substitution $\frac{1}{t} = u \implies \frac{1}{t^2} \, dt = -du$. Note the limits will still be from $-\infty$ to $\infty$ because if we split the integral at $0$, we take the limit to $0$ from below for the integral that goes from $-\infty$ to $0$, leaving us with:
$$f(3a, \sqrt{3} \, b) = \sqrt{3} e^{-a} \int_{-\infty}^{\infty} \left(\frac{e^{\frac{a+i b/u}{1/u^2 + 1}}}{1+1/u^2} - e^{a+ i b/u - 1/u^2} \right) \, du+\sqrt{3\pi}\left(2e^{-b^2/4}-b\sqrt{\pi}\, \, \text{erfc} \,\left(\frac{b}{2}\right)\right)$$
$$=\sqrt{3} e^{-a} \int_{-\infty}^{\infty} \left(\frac{u^2 e^{\frac{a u^2+i b u}{u^2+1}}}{u^2+1} - e^{a+i b/u-1/u^2}\right) \, du+\sqrt{3\pi}\left(2e^{-b^2/4}-b\sqrt{\pi}\, \, \text{erfc} \,\left(\frac{b}{2}\right)\right)$$
Since $\frac{u^2}{1+u^2} = 1-\frac{1}{u^2+1}$ we have:
$$f(3a, \sqrt{3} \, b) = \sqrt{3}\int_{-\infty}^{\infty}\frac{e^{\frac{-a+i bt}{1+t^2}}}{1+t^2}\, dt -\sqrt{3}\int_{-\infty}^{\infty}\left(e^{\frac{-a+i bt}{1+t^2}}-e^{-1/t^2+i b/t}\right) \, dt+\sqrt{3\pi}\left(2e^{-b^2/4}-b\sqrt{\pi}\,\text{erfc}\,\left(\frac{b}{2}\right)\right)$$
$$\sqrt{3}\int_{-\infty}^{\infty}\frac{e^{\frac{-a+i bt}{1+t^2}}}{1+t^2}\, dt = \sqrt{3} e^{-a/2}\int_{-\pi/2}^{\pi/2}e^{-a/2\cos(2u)+ib/2\sin(2u)}\,du= \sqrt{3} \pi e^{-a/2} I_0 \left(\frac{\sqrt{a^2-b^2}}{2}\right)$$
This leaves us with the following final expression:
$$f(3a, \sqrt{3} \, b) = \sqrt{3}\pi e^{-a/2} I_0 \left(\frac{\sqrt{a^2-b^2}}{2}\right) +\sqrt{3\pi}\left(2e^{-b^2/4}-b\sqrt{\pi}\,\text{erfc}\,\left(\frac{b}{2}\right)\right) -\sqrt{3}\int_{-\infty}^{\infty}\left(e^{\frac{-a+i bt}{1+t^2}}-e^{-1/t^2+i b/t}\right) \, dt$$
It is not currently clear to me how to evaluate this final integral. It is fairly trivial to determine the latter $e^{-1/t^2+i b/t}$ half of it through a Mellin transform method, however, I cannot do the same for the former half.
EDIT
From @Yuri Negometyanov’s excellent answer to OP’s related question we have:
$$f(3a,\sqrt{3}\, b) = - \sqrt{3\pi } \sum_{m=1}^{\infty } \frac{(-a)^m \Gamma \left(m-\frac{1}{2}\right) \,{}_1F_2\left(m-\frac{1}{2};\frac{m+1}{2},\frac{m}{2};-\frac{b^2}{16}\right)}{(m-1)! \, m!}+\frac{\sqrt{3} \pi b^2}{4} \,{}_1F_2\left(\frac{1}{2};\frac{3}{2},2;-\frac{b^2}{16}\right)+\sqrt{3}\pi e^{-a/2} \,{}_0\tilde{F}_1\left(;1;\frac{a^2-b^2}{16} \right)-\sqrt{3} \pi b$$
Where $\tilde{F}$ is the regularised hypergeometric function (which in this case can be expressed in terms of Bessel functions).
NIntegrate[NIntegrate[Exp[(-t^2 + I*t)/(3*t^2 + 1) + I*t*x]*x/(3*t^2 + 1), {t, -Infinity,Infinity}, WorkingPrecision -> 20], {x, 0, Infinity}]
works. The result is 3.49233 in MMA 12.3 $\endgroup$