We can move and touch each square only once as shown in this picture. Start at the bottom right square
But we cannot end on the square left to the start square.
Such a tour consists of $l$ moves to the left, $d$ moves down and $x$ moves diagonal upright. The following equations hold:
$$l+d+x=63$$
because we touch every square of the $8\times 8$ squares exactly once.
$$d=x$$
because we end up in the same row as we started, so the number of down moves ($d$) must be equal to the number of up moves that can be only achieved by the diagonal moves($x$).
Finally the number of left moves($l$) must be one more than the number of right moves($x$), so
$$l=x+1$$
From this we get
$$(x+1)+x+x=63$$
which has no integer solution.
This argument works for all square boards because $n^2-2$ is not divisible by $3$ for any $n$.