According to Solving Non Negative Constrained Least Squares by Analogy with Least Squares (MATLAB) and all resources I have looked up regarding this topic, the non-negative least squares problem
$$ \min \frac 1 2 || \Phi w - y ||^2, \\ \text{s.t} \, w_i \ge 0 $$ has no closed form solution. But what if we naively do Lagrangian constraint optimization? The Lagrangian is given by $$ L(w, \lambda) = \frac 1 2 (\Phi w - y)^T(\Phi w - y) - \lambda^T w $$ Taking the derivative w.r.t $w$ and setting it to $0$, we get the optimal primal solution $$ w^* = (\Phi^T \Phi)^{-1} (\Phi^T y + \lambda). $$ Looking at the dual function $g(\lambda) = L(w^*, \lambda)$, its derivative is given by $$ \frac {\text{d}g} {\text d \lambda} = - (\Phi^T \Phi)^{-1} (\Phi^T y + \lambda). $$ Setting it to zero yields $$ \lambda = - \Phi^T y. $$ However, we have the constraint that all multipliers need to be non-negative. This results in the dual solution $$ \lambda^* = \max(- \Phi^T y, 0), $$ where the $\max$ operator is defined per dimension. This results in the closed form solution
$$ w^* = (\Phi^T \Phi)^{-1} (\Phi^T y + \max(- \Phi^T y, 0)). $$
Am I going wrong somewhere? If so, where?