So far I get the below:
To prove the above statement with contrapositive, we need to show that if $a+b \leq 1$ then $a^2 + b^2 \ne 1$. If $a+b \leq 1$, then $a \leq 1 - b$. If we square both sides of the inequality we get $a^2 \leq (1 - b)^2$, which is $a^2 \leq 1 - 2b + b^2$, then $a^2 - b^2 \leq 1 - 2b$.
I get to this step but I get $a^2 - b^2$ instead of $a^2 + b^2$, I don't know if I am on the right track or if it is possible to prove with contrapositive?