Suppose $\mathcal{C}$ is monoidal closed, with tensor product
$- \otimes -$ and internal hom $[-,-]$. Suppose we have adjoint functors $L,R \colon \mathcal{C} \to \mathcal{C}$ that 'internalize', by which I mean there's a natural isomorphism
$$ [LX, Y] \cong [X, RY] .$$
Then up to natural isomorphism $L$ must be given by tensoring by some object $A$, and $R$ must be $[A , -]$. That is, there must exist natural isomorphisms
$$ LX \cong X \otimes A $$
and
$$ RX \cong [A, X]. $$
Conversely, any functor of the form $LX \cong X \otimes A$ does internalize in this way.
To see these facts, first remember the proof that any functor of the form $LX \cong X \otimes A$ does internalize:
$$ [X \otimes A, Y] \cong [X, [A, Y]]. $$
By the Yoneda lemma, this is equivalent to
$$ \mathrm{hom}(Z, [X \otimes A, Y]) \cong \mathrm{hom}(Z, [X, [A, Y]]) .$$
where the isomorphism is natural in all four arguments. Using the hom-tensor adjunction once on each side, this is equivalent to
$$ \mathrm{hom}(Z \otimes X \otimes A, Y) \cong \mathrm{hom}(Z \otimes X, [A, Y]]) $$
and using it again on the right side, this is equivalent to
$$ \mathrm{hom}(Z \otimes X \otimes A, Y) \cong \mathrm{hom}(Z \otimes X \otimes A, Y) $$
so we're done!
Now let's try to copy this argument starting from an arbitrary pair of adjoint functors $L, R \colon \mathcal{C} \to \mathcal{C}$. When do we have a natural isomorphism
$$ [LX, Y] \cong [X, RY] ? $$
By the Yoneda lemma, this is equivalent to
$$ \mathrm{hom}(Z, [LX, Y]) \cong \mathrm{hom}(Z, [X, RY]) .$$
where the isomorphism is natural in all four arguments. Using the hom-tensor adjunction once on each side, this is equivalent to
$$ \mathrm{hom}(Z \otimes LX, Y) \cong \mathrm{hom}(Z \otimes X, RY) $$
and using the adjunction between $L$ and $R$, this is equivalent to
$$ \mathrm{hom}(Z \otimes LX, Y) \cong \mathrm{hom}(L(Z \otimes X), Y) $$
Using the Yoneda lemma again, this is equivalent to
$$ Z \otimes LX \cong L(Z \otimes X) \qquad (\star) $$
In short, the existence of a natural isomorphism $[LX, Y] \cong [X, RY]$ is equivalent to $(\star)$.
But if $(\star)$ holds, we can take $X$ to be the unit of the tensor product and see
$$ Z \otimes LI \cong L(Z \otimes I) \cong LZ $$
It follows that up to natural isomorphism, $L$ must be given by tensoring with the object $A = LI$:
$$ LZ \cong Z \otimes A$$
Note that we never needed $\mathcal{C}$ to be symmetric.