Note that
$$x^{-y} = \frac{1}{x^y}$$
whenever this quantity is defined. In your case we have $y=3/2$ and $x=100/9$. Therefore,
$$\left( \frac{100}{9} \right)^{-3/2} = \frac{1}{(100/9)^{3/2}}$$
You can then split this fraction up, because
$$\frac{1}{a/b} = \frac{b}{a}$$
In this case, $a=100^{3/2}$ and $b=9^{3/2}$. Thus,
$$\left( \frac{100}{9} \right)^{-3/2} = \frac{1}{(100/9)^{3/2}} = \frac{9^{3/2}}{100^{3/2}}$$
Of course, if you want to pull out that power of $3/2$ and use it on the entire fraction, that works too:
$$\left( \frac{100}{9} \right)^{-3/2} = \frac{1}{(100/9)^{3/2}} = \frac{9^{3/2}}{100^{3/2}} = \left( \frac{9}{100} \right)^{3/2}$$
An alternate way to frame this is that
$$(x^y)^z = x^{yz} = (x^z)^y$$
Thus,
$$\left( \frac{100}{9} \right)^{-3/2}
= \left( \left( \frac{100}{9} \right)^{-1} \right)^{3/2}
$$
Then, since $x^{-1} = 1/x$, we flip the inside
$$\left( \frac{100}{9} \right)^{-3/2}
= \left( \left( \frac{100}{9} \right)^{-1} \right)^{3/2}
= \left( \frac{9}{100} \right)^{3/2}
$$
In short, either method works. (Just be sure you know why each works!)