The answer by orangeskid is correct and makes good points on topic, but I would like to add another answer because I think there is a confusion / misunderstanding in the question which should be pointed out explicitly.
Namely, there are at least three ways to switch between complex and real Lie groups / algebras.
One way "up": Start with a real Lie group / algebra and complexify. If you start with something of real dimension $n$, then you get out something of complex dimension $n$. This is often called scalar extension. It can be described as a functor.
One out of two possible ways "down": Start with a complex Lie group / algebra and "forget" its complex structure, just "view it as a real Lie group / algebra". If you start with something of complex dimension $n$, then you get out something of real dimension $\color{red}{2}n$. This is often called scalar restriction. It can be described as a functor.
The other of two possible ways "down". Start with a complex Lie group / algebra and try (!) to find a (!) real Lie group / algebra such that, when you complexify it, you get the complex Lie group / algebra you started with. Such a thing is called a real form. If your complex object has complex dimension $n$, then a real form must have real dimension $n$.
The problem with 3 is that in general we neither have existence nor uniqueness, in other words A) not every complex Lie group / algebra has real forms, B) but some complex Lie groups / algebras have many different real forms.
Problem B) is what you ask about in your question 1, and as the other answer points out, indeed e.g. $SL_n(\mathbb C)$ has more than $\lfloor \frac{n}{2} \rfloor +1$ mutually non-isomorphic real forms, namely $SU(k,n-k)$ for $k = 0,..., \lfloor \frac{n}{2} \rfloor$ (actually there are even more: For $n \ge 3$, the standard split form $SL_n(\mathbb R)$ is not isomorphic to any of the list so far, and for $n \ge 4$ also $SL_n(\mathbb H)$ gives another form not isomorphic to the ones so far.) Likewise, all $SO(p,q)$ are real forms of $SO_{p+q}(\mathbb C)$ etc.
Problem A) has not been addressed so far here. A standard example of a complex Lie algebra which does not have a real form is described in the answer to Is every complex Lie algebra a complexification?.
Now problems A and B show quite clearly that the procedure no. 3, finding a real form to a complex Lie grouo / algebra, is not at all described by a functor (unless, maybe, if one restricted to tiny subcategories of the categories in question). In particular:
Do not mix up the forgetful functor "scalar restriction" with the task of "finding a real form"!
Because scalar restriction is a forgetful functor, but never finds you a real form (unless your object is $0$-dimensional), whereas real forms do not per se behave functorially, in fact they do not exist in general, and if they do, they are not unique in general.
More about all this in "Fact 2" of this answer https://math.stackexchange.com/a/4184237/96384, and in the bulk of https://math.stackexchange.com/a/3895802/96384 (for a long while this just talks about scalar extension and restriction and how they are not inverse to each other; see the "Added in response to comment" part to discuss real forms, i.e. method 3, born out of a desire to find "an inverse" to complexification which scalar restriction is not.)
That all being said, I think you do mix up what you shouldn't in your questions 2 and 3. It turns out though that they can be answered either way you would clarify them:
If in question 2 you mean, are there non-isomorphic complex Lie groups whose scalar restrictions are isomorphic as real Lie groups: Yes, as pointed out in orangeskid's answer, all elliptic curves over $\mathbb C$, when one forgets their complex structure, just happen to be isomorphic to the real Lie group $\mathbb R^2 / \mathbb Z^2$. But there are many non-isomorphic (as complex Lie groups) elliptic curves over $\mathbb C$ (cf. Elliptic curves $\mathbb C/\Gamma , \mathbb C/\Gamma'$ are isomorphic iff $\Gamma=\lambda\Gamma'.$ or any introduction to elliptic curves).
If in question 2 you mean, are there non-isomorphic complex Lie groups which have real forms that are isomorphic: Then by definition, this cannot happen.
If in question 3 you mean, is there a real Lie group which is not the image of the scalar restriction functor applied to some complex Lie group: Then clearly, every real Lie group of odd dimension (like $\mathbb R$ itself) is an example. (Many even-dimensional ones exist as well, but there one needs to look closer.)
If in question 3 you mean, is there a real Lie group which is not a real form of a complex Lie group: Then again by definition, this cannot happen, because by definition any real Lie group is a real form of its own complexification.