Partial result using probabilistic methods (but the result is deterministic). I claim that, for any $n$, you can choose the generators so that the pairwise sums will miss at most $31$ of the target binary sequences.
I'll use $\oplus$ for the XOR sum. Let $X_1,\ldots,X_k$ be $k=2^{n-2}$ bit-strings chosen independently uniformly at random (the "generators"). I claim that the $m=\binom k2$ pairwise sums $Y_{ij} := X_i \oplus X_j$, $i\ne j$, are uniformly distributed and pairwise independent. We have
$$
\newcommand{\P}{\mathbb P}
\newcommand{\E}{\mathbb E}
\newcommand{\V}{\mathbb V}
\P(Y_{ij} = y) = \sum_{x}\P(X_j = y \oplus x) \P(X_i = x) = 2^{-n},
$$
proving that they're uniform. It's clear that $Y_{ij}$ and $Y_{kl}$ are independent for $i,j,k,l$ distinct. In the case $l=i$, we have
$$ \begin{split}
\P(Y_{ij} = y_1 \wedge Y_{ik} = y_2)
&= \sum_{x}\P(X_j = y_1 \oplus x \wedge X_k = y_2\oplus x) \P(X_i = x) \\
&= \sum_{x}\P(X_j = y_1 \oplus x) \P(X_k = y_2\oplus x) \P(X_i = x) \\
&= 2^{-2n},
\end{split} $$
proving pairwise independence. Note that they're not 3-independent though, as $Y_{ij} \oplus Y_{ik} = Y_{jk}$.
Now let $I_{ij}^y$ be the indicator variable of the event that $Y_{ij}=y$, and let $I^y = \sum_{i<j}I_{ij}^y$. Let $J^y$ indicate that $I^y=0$, i.e. that we miss $y$. Let $p=2^{-n}$. We have $\E I^y = mp$ and $\V I^y=mp(1-p)$ (here we use pairwise independence). Using Cantelli's inequality (the one-sided version of Chebyshev), we get
$$
\E J^y
= \P(I^y = 0)
\le \P(I^y-\E I^y \le -\E I^y)
\le \frac{\V I^y}{\V I^y + (\E I^y)^2}
= \frac{1-p}{1-p+mp}.
$$
Note that $m=2^{2n-5} - 2^{n-3}$, which gives us
$$
\E(\textrm{number of misses})
= \E\left(\sum_y J^y\right)
\le 2^n \frac{1-p}{1-p+mp}
< 32
$$
for all $n$. Since the expected number of misses is $<32$, there must exist some choice of the $X_i$'s that has $\le 31$ misses.
Note that if we had used Chebyshev instead of Cantelli, we would get the weaker result of $\le 32$ misses for $n\ge 8$.
By the way, here are the bounds way get for each $n$:
$$
\begin{array}{c|c}
n&1&2&3&4&5&6&7&8&9&\ge10 \\
\hline
\textrm{Bound}&(2)&(4)&7&11&16&22&26&28&30&31 \\
\hline
\textrm{Bound}/2^n &(1)&(1)&.86&.69&.50&.34&.20&.11&.059&\to0
\end{array}
$$