Define the function $\mathcal{I}:\mathbb{R}_{>0}\rightarrow\mathbb{R}$ via the (convergent) improper integral
$$\mathcal{I}{\left(a\right)}:=-8\int_{0}^{a}\mathrm{d}x\,\frac{\arctan{\left(x\right)}\ln{\left(1-a^{-2}x^{2}\right)}}{1+x^{2}}.\tag{1}$$
This answer will consider the problem of the general evaluation of $\mathcal{I}$ and obtain a closed-form expression for it in terms of elementary functions and polylogarithms.
Note that this includes the OP's integral as the following particular value:
$$-\frac18\mathcal{I}{\left(\frac{1}{\sqrt{3}}\right)}=\int_{0}^{\frac{1}{\sqrt{3}}}\mathrm{d}x\,\frac{\arctan{\left(x\right)}\ln{\left(1-3x^{2}\right)}}{1+x^{2}}\approx-0.124354.$$
Recall that the standard Clausen functions are defined by the following Fourier series:
$$\operatorname{Cl}_{2m}{\left(\theta\right)}:=\sum_{n=1}^{\infty}\frac{\sin{\left(n\theta\right)}}{n^{2m}};~~~\small{m\in\mathbb{N}\land\theta\in\mathbb{R}},\tag{2a}$$
$$\operatorname{Cl}_{2m+1}{\left(\theta\right)}:=\sum_{n=1}^{\infty}\frac{\cos{\left(n\theta\right)}}{n^{2m+1}};~~~\small{m\in\mathbb{N}\land\theta\in\mathbb{R}}.\tag{2b}$$
The Clausen function of order $2$ may also be given by the integral representation
$$\operatorname{Cl}_{2}{\left(\theta\right)}=-\int_{0}^{\theta}\mathrm{d}\varphi\,\ln{\left(\left|2\sin{\left(\frac{\varphi}{2}\right)}\right|\right)};~~~\small{\theta\in\mathbb{R}}.$$
The following pair of special values and pair of derivatives are obtained directly from the Fourier series definitions $(2)$:
$$\operatorname{Cl}_{2m}{\left(\theta\right)}=0;~~~\small{m\in\mathbb{N}},$$
$$\operatorname{Cl}_{2m+1}{\left(0\right)}=\sum_{n=1}^{\infty}\frac{1}{n^{2m+1}}=\zeta{\left(2m+1\right)};~~~\small{m\in\mathbb{N}},$$
$$\frac{d}{d\theta}\operatorname{Cl}_{2m+1}{\left(\theta\right)}=-\operatorname{Cl}_{2m}{\left(\theta\right)};~~~\small{m\in\mathbb{N}\land\theta\in\mathbb{R}},$$
$$\frac{d}{d\theta}\operatorname{Cl}_{2m+2}{\left(\theta\right)}=\operatorname{Cl}_{2m+1}{\left(\theta\right)};~~~\small{m\in\mathbb{N}\land\theta\in\mathbb{R}}.$$
Then, the following integration formulas for higher order Clausen functions follow quite simply from the fundamental theorem of calculus:
$$\int_{0}^{\theta}\mathrm{d}\varphi\,\operatorname{Cl}_{2m}{\left(\varphi\right)}=\zeta{\left(2m+1\right)}-\operatorname{Cl}_{2m+1}{\left(\theta\right)};~~~\small{m\in\mathbb{N}\land\theta\in\mathbb{R}},$$
$$\int_{0}^{\theta}\mathrm{d}\varphi\,\operatorname{Cl}_{2m+1}{\left(\varphi\right)}=\operatorname{Cl}_{2m+2}{\left(\theta\right)};~~~\small{m\in\mathbb{N}\land\theta\in\mathbb{R}}.$$
Suppose $a\in\mathbb{R}_{>0}$, and set $\alpha:=\arctan{\left(a\right)}$. Then, $0<\alpha<\frac{\pi}{2}\land a=\tan{\left(\alpha\right)}$, and we find
$$\begin{align}
\mathcal{I}{\left(a\right)}
&=-8\int_{0}^{a}\mathrm{d}x\,\frac{\arctan{\left(x\right)}\ln{\left(1-a^{-2}x^{2}\right)}}{1+x^{2}}\\
&=-8\int_{0}^{\tan{\left(\alpha\right)}}\mathrm{d}x\,\frac{\arctan{\left(x\right)}\ln{\left(1-\cot^{2}{\left(\alpha\right)}x^{2}\right)}}{1+x^{2}}\\
&=-8\int_{0}^{\alpha}\mathrm{d}\varphi\,\varphi\ln{\left(1-\cot^{2}{\left(\alpha\right)}\tan^{2}{\left(\varphi\right)}\right)};~~~\small{\left[\arctan{\left(x\right)}=\varphi\right]}\\
&=-8\int_{0}^{\alpha}\mathrm{d}\varphi\,\varphi\ln{\left(\frac{\sin^{2}{\left(\alpha\right)}\cos^{2}{\left(\varphi\right)}-\cos^{2}{\left(\alpha\right)}\sin^{2}{\left(\varphi\right)}}{\sin^{2}{\left(\alpha\right)}\cos^{2}{\left(\varphi\right)}}\right)}\\
&=-8\int_{0}^{\alpha}\mathrm{d}\varphi\,\varphi\ln{\left(\csc^{2}{\left(\alpha\right)}\sec^{2}{\left(\varphi\right)}\sin{\left(\alpha-\varphi\right)}\sin{\left(\alpha+\varphi\right)}\right)}\\
&=8\int_{0}^{\alpha}\mathrm{d}\varphi\,\varphi\left[\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+\ln{\left(\cos^{2}{\left(\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha-\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha+\varphi\right)}\right)}\right]\\
&=8\int_{0}^{\alpha}\mathrm{d}\varphi\,\varphi\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}\\
&~~~~~+8\int_{0}^{\alpha}\mathrm{d}\varphi\,\varphi\left[2\ln{\left(\cos{\left(\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha-\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha+\varphi\right)}\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}\\
&~~~~~+8\int_{0}^{\alpha}\mathrm{d}\varphi\int_{0}^{\varphi}\mathrm{d}\vartheta\,\left[2\ln{\left(\cos{\left(\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha-\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha+\varphi\right)}\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}\\
&~~~~~+8\int_{0}^{\alpha}\mathrm{d}\vartheta\int_{\vartheta}^{\alpha}\mathrm{d}\varphi\,\left[2\ln{\left(\cos{\left(\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha-\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha+\varphi\right)}\right)}\right].\\
\end{align}$$
Then,
$$\begin{align}
\mathcal{I}{\left(a\right)}
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}\\
&~~~~~+8\int_{0}^{\alpha}\mathrm{d}\vartheta\int_{\vartheta}^{\alpha}\mathrm{d}\varphi\,\left[2\ln{\left(\cos{\left(\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha-\varphi\right)}\right)}-\ln{\left(\sin{\left(\alpha+\varphi\right)}\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}\\
&~~~~~+8\int_{0}^{\alpha}\mathrm{d}\vartheta\int_{\vartheta}^{\alpha}\mathrm{d}\varphi\,\left[-\ln{\left(2\sin{\left(\alpha-\varphi\right)}\right)}-\ln{\left(2\sin{\left(\alpha+\varphi\right)}\right)}+2\ln{\left(2\cos{\left(\varphi\right)}\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}\\
&~~~~~+8\int_{0}^{\alpha}\mathrm{d}\vartheta\,\bigg{[}-\int_{\vartheta}^{\alpha}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\alpha-\varphi\right)}\right)}-\int_{\vartheta}^{\alpha}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\alpha+\varphi\right)}\right)}\\
&~~~~~+2\int_{\vartheta}^{\alpha}\mathrm{d}\varphi\,\ln{\left(2\cos{\left(\varphi\right)}\right)}\bigg{]}\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}\\
&~~~~~+8\int_{0}^{\alpha}\mathrm{d}\vartheta\,\bigg{[}-\int_{0}^{\alpha-\vartheta}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\varphi\right)}\right)}-\int_{\alpha+\vartheta}^{2\alpha}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\varphi\right)}\right)}\\
&~~~~~+2\int_{\frac{\pi}{2}-\alpha}^{\frac{\pi}{2}-\vartheta}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\varphi\right)}\right)}\bigg{]}\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+4\int_{0}^{\alpha}\mathrm{d}\vartheta\,\bigg{[}-\int_{0}^{2\alpha-2\vartheta}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\frac{\varphi}{2}\right)}\right)}\\
&~~~~~-\int_{2\alpha+2\vartheta}^{4\alpha}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\frac{\varphi}{2}\right)}\right)}+2\int_{\pi-2\alpha}^{\pi-2\vartheta}\mathrm{d}\varphi\,\ln{\left(2\sin{\left(\frac{\varphi}{2}\right)}\right)}\bigg{]};~~~\small{\left[\varphi\mapsto\frac{\varphi}{2}\right]}\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+4\int_{0}^{\alpha}\mathrm{d}\vartheta\,\bigg{[}\operatorname{Cl}_{2}{\left(2\alpha-2\vartheta\right)}\\
&~~~~~+\operatorname{Cl}_{2}{\left(4\alpha\right)}-\operatorname{Cl}_{2}{\left(2\alpha+2\vartheta\right)}+2\operatorname{Cl}_{2}{\left(\pi-2\alpha\right)}-2\operatorname{Cl}_{2}{\left(\pi-2\vartheta\right)}\bigg{]},\\
\end{align}$$
and then,
$$\begin{align}
\mathcal{I}{\left(a\right)}
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+4\int_{0}^{\alpha}\mathrm{d}\vartheta\,\bigg{[}\operatorname{Cl}_{2}{\left(2\alpha-2\vartheta\right)}\\
&~~~~~+2\operatorname{Cl}_{2}{\left(2\alpha\right)}-\operatorname{Cl}_{2}{\left(2\alpha+2\vartheta\right)}-2\operatorname{Cl}_{2}{\left(\pi-2\vartheta\right)}\bigg{]}\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+8\alpha\operatorname{Cl}_{2}{\left(2\alpha\right)}\\
&~~~~~+4\int_{0}^{\alpha}\mathrm{d}\vartheta\,\left[\operatorname{Cl}_{2}{\left(2\alpha-2\vartheta\right)}-\operatorname{Cl}_{2}{\left(2\alpha+2\vartheta\right)}-2\operatorname{Cl}_{2}{\left(\pi-2\vartheta\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+8\alpha\operatorname{Cl}_{2}{\left(2\alpha\right)}\\
&~~~~~+2\int_{0}^{2\alpha}\mathrm{d}\vartheta\,\left[\operatorname{Cl}_{2}{\left(2\alpha-\vartheta\right)}-\operatorname{Cl}_{2}{\left(2\alpha+\vartheta\right)}-2\operatorname{Cl}_{2}{\left(\pi-\vartheta\right)}\right];~~~\small{\left[\vartheta\mapsto\frac{\vartheta}{2}\right]}\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+8\alpha\operatorname{Cl}_{2}{\left(2\alpha\right)}\\
&~~~~~+2\left[\int_{0}^{2\alpha}\mathrm{d}\vartheta\,\operatorname{Cl}_{2}{\left(2\alpha-\vartheta\right)}-\int_{0}^{2\alpha}\mathrm{d}\vartheta\,\operatorname{Cl}_{2}{\left(2\alpha+\vartheta\right)}-2\int_{0}^{2\alpha}\mathrm{d}\vartheta\,\operatorname{Cl}_{2}{\left(\pi-\vartheta\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+8\alpha\operatorname{Cl}_{2}{\left(2\alpha\right)}\\
&~~~~~+2\left[\int_{0}^{2\alpha}\mathrm{d}\vartheta\,\operatorname{Cl}_{2}{\left(\vartheta\right)}-\int_{2\alpha}^{4\alpha}\mathrm{d}\vartheta\,\operatorname{Cl}_{2}{\left(\vartheta\right)}-2\int_{\pi-2\alpha}^{\pi}\mathrm{d}\vartheta\,\operatorname{Cl}_{2}{\left(\vartheta\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+8\alpha\operatorname{Cl}_{2}{\left(2\alpha\right)}\\
&~~~~~+2\left[\operatorname{Cl}_{3}{\left(0\right)}-\operatorname{Cl}_{3}{\left(2\alpha\right)}+\operatorname{Cl}_{3}{\left(4\alpha\right)}-\operatorname{Cl}_{3}{\left(2\alpha\right)}+2\operatorname{Cl}_{3}{\left(\pi\right)}-2\operatorname{Cl}_{3}{\left(\pi-2\alpha\right)}\right]\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+8\alpha\operatorname{Cl}_{2}{\left(2\alpha\right)}\\
&~~~~~+2\operatorname{Cl}_{3}{\left(0\right)}+4\operatorname{Cl}_{3}{\left(\pi\right)}+2\operatorname{Cl}_{3}{\left(4\alpha\right)}-4\operatorname{Cl}_{3}{\left(2\alpha\right)}-4\operatorname{Cl}_{3}{\left(\pi-2\alpha\right)}\\
&=4\alpha^{2}\ln{\left(\sin^{2}{\left(\alpha\right)}\right)}+8\alpha\operatorname{Cl}_{2}{\left(2\alpha\right)}-\zeta{\left(3\right)}+\operatorname{Cl}_{3}{\left(4\alpha\right)}.\blacksquare\\
\end{align}$$
For the particular case in which $a=\frac{1}{\sqrt{3}}$, we then have $\alpha=\arctan{\left(\frac{1}{\sqrt{3}}\right)}=\frac{\pi}{6}$, and hence
$$\begin{align}
\mathcal{I}{\left(\frac{1}{\sqrt{3}}\right)}
&=4\left(\frac{\pi}{6}\right)^{2}\ln{\left(\sin^{2}{\left(\frac{\pi}{6}\right)}\right)}+8\cdot\frac{\pi}{6}\operatorname{Cl}_{2}{\left(2\cdot\frac{\pi}{6}\right)}-\zeta{\left(3\right)}+\operatorname{Cl}_{3}{\left(4\cdot\frac{\pi}{6}\right)}\\
&=-\frac{2\pi^{2}}{9}\ln{\left(2\right)}+\frac{4\pi}{3}\operatorname{Cl}_{2}{\left(\frac{\pi}{3}\right)}-\zeta{\left(3\right)}+\operatorname{Cl}_{3}{\left(\frac{2\pi}{3}\right)}\\
&=\frac{4\pi}{3}G-\frac{13}{9}\zeta{\left(3\right)}-\frac{2\pi^{2}}{9}\ln{\left(2\right)},\\
\end{align}$$
where here $G$ denotes Gieseking's constant.