I am trying to follow Hatcher's proof of Poincaré Duality on p. 248.
Suppose $M$ is an $R$-oriented manifold. We have first defined $H^k_c(M;R)$ to be the direct limit of groups $H^k(M,M\setminus K;R)$ where we take some compact subset $K\subset M$. We define a duality map $$D_M:H^k_c(M;R)\to H_{n-k}(M;R)$$ which sends $[\phi]$ with $\phi\in H^k(M,M\setminus K;R)$ to $\phi\smallfrown\mu_K$. Where $\mu_K$ is the unique class in $H_n(M,M\setminus K;R)$ which for all $x\in K$ gets mapped to the local orientation at $x$ under the inclusion induced morphism $$H_n(M,M\setminus K;R)\to H_n(M,M\setminus \{x\};R)$$
The noncompact version of Poincaré Duality then says the following:
For an $R$-oriented $n$-manifold $M$ the duality map $$D_M:H^k_c(M;R)\to H_{n-k}(M;R)$$ is an isomorphism for all $k$.
The proof is inductive and begins with the observation that it holds for $M=\mathbb{R}^n$.
I do not know how one explicitly makes this identification $H^k(\mathbb{R}^n;R)\to H^k_c(\Delta^n,\partial\Delta^n)$ and why the map turns into the cap product with the class represented by the identity.
Another method I looked into was via an isomorphism $$H^k(\mathbb{R}^n,\mathbb{R}^n\setminus B)\to H^k_c(\mathbb{R}^n;R)$$ where $B$ is a closed ball around the origin. The duality map then becomes the cap product with $\mu_K$, but I am not sure how to finish the argument here.
A similar question was asked here, but no answers were given and I was unable to translate the comments into something concrete.