Let's assume the usual setup of non-negative, measurable functions on a space with finite Lebesgue measure. Bounded functions are integrable, but there are many integrable functions that are not bounded. A natural question therefore, is "how unbounded can they be?" Chebyshev gives a quantitative answer: in rough terms, it says that an integrable function cannot be too large on large sets, with the power law type decay $m(f>r)\le C/r$.
(When $r$ is too small the inequality becomes rather weak especially in probability theory or when your measure space is otherwise finite so let’s ignore that scenario.)
One could guess that something like Chebyshev should hold by checking the inequality on 'spike functions' $x^{-s}$ for $s>0$. For the range $s\in(0,1)$, $x^{-s}$ are in $L^1([0,1])$ despite being unbounded. In this case, for $r>1$ $$m(x^{-s}>r)= m((0,r^{-1/s}))=\frac1{r^{1/s}} < \frac 1r $$ since $r^{1/s}>r$, in turn since $1/s>1$.
If we allow $s$ to be too big i.e. $s>1$ i.e. $1/s<1$, then the inequality reverses:
$$ \frac 1{r^{1/s}} > \frac1r$$
So we cannot expect the inequality of Chebyshev type to hold with the decay $1/r$, even if we replace the factor $\int f dx$ by something finite.
It’s interesting that the borderline case of $1/x$ which is $s=1$ just barely fails to be integrable; one manifestation of this is that it achieves the $1/r$ bound exactly. Another way to rephrase Chebyshev is therefore that integrable functions are dominated by (a rearrangement of) $C/x$. This actually leads one to consider the ‘weak $L^1$ space’ which is essentially a space of functions for which we have Chebyshev’s inequality (but not necessarily $L^1$ control). This space turns out to be very useful in harmonic analysis (see for example, the Marcinkiewicz interpolation theorem and its application to the Hardy-Littlewood maximal function).
Finally I note that we can actually refine Chebyshev into a comparison with other power laws $1/x^s$, or even any decreasing function. This comes from first rewriting the set before applying Chebyshev
$$m(f>r)=m(f^s > r^s) \le \frac{\|f\|_{L^s}^s}{r^s}$$
This lets you recover the sharp decay of other power laws as well.
Setting $s=2$ is usually what Probabilists call Chebyshev ($s=1$ is then called Markov's inequality) but you can trivially do the same trick with any increasing function instead of $x^s$; a very useful variation in extremal probability theory is the Chernoff bound
$$m(f>r)\le \frac{\|e^{tf}\|_{L^1}}{e^{tr}}$$ which gives exponential decay, if you can control the moment generating function.