Of course! Let $G$ act on itself by conjugation; that is, $g\cdot x=gxg^{-1}$. Then $G$ divides itself into orbits; each orbit is a conjugacy class. The center is the set of size-$1$ conjugacy classes; that is, the fixed points.
By the orbit-stabilizer relation, each orbit has size dividing the order of $G$. In this case, that there are (possibly) orbits of size $1$, $2$, $4$, $8$, and $16$. Let there be $n_1$-, $n_2$-, $n_4$-, $n_8$-, and $n_{16}$-many such orbits (respectively). Then we know that $n_1=2$, and seek to show $n_2>0$. Since $G$ is not one giant orbit, we must have $n_{16}=0$. Counting elements, $$16=|G|=n_1+2n_2+4n_4+8n_8$$ Substituting in $n_1$, we obtain
$$\begin{align}
2\cdot 7=14 &=2n_2+4n_4+8n_8\\
&=2(n_2+2n_4+4n_8).
\end{align}$$
Now divide by two and take the result mod $2$. Then $$1\equiv n_2\pmod{2}$$ In particular, $n_2$ cannot be $0$, as desired.
Obviously, this argument can be generalized: if $G$ has order $p^n$ and a center of size $p^k$, then $G$ must have a conjugacy class of size $p^k$ as well.