Since $U(-1,1)$ is a continuous distribution, $\Pr(X=k|X^2=x^2)$ is not well defined. Instead you first find the CDF given $u \leqslant X^2 \leqslant u+\Delta u$, for some small $\Delta u$ (you can assume it's positive), then take the derivative w.r.t. $k$, and let $\Delta u \to 0$ to get your conditional PDF.
So in this case your unconditional probability is
$$
\Pr(u \leqslant X^2 \leqslant u+\Delta u)=\sqrt{u+\Delta u} - u. \tag 1
$$
Then you need to calculate
$$
\Pr(X \leqslant k \text{ and } u \leqslant X^2 \leqslant u+\Delta u).\tag 2
$$
This is a piece-wise linear function of $k$. I will leave the details to you.
Finally you calculate the ratio of (2) to (1), take the derivative, let $\Delta u \to 0$, you will get your conditional probability mass function.
============
Update:
I found this interesting: https://www.probabilitycourse.com/chapter4/4_3_2_delta_function.php
It basically says that the "symbolic derivative" of the Heavyside step function $u(x)$ is the Dirac delta function $\delta(x)$, where
$$
u(x) = \begin{cases} 1, & x\geqslant 0 \\ 0, & x < 0 \end{cases}
$$
and
$$
\delta(x) = \begin{cases} \infty, & x=0 \\ 0, & \text{elsewhere} \end{cases}
$$
And any discrete distribution has a generalized PDF in terms of the delta function:
$$
f_X(x) = \sum \Pr(X=x_k) \delta (x-x_k).
$$
Now back to OP's question. We look at the joint distribution of $(X,Y)$ on $[-1,1] \times [0,1]$, where $X \sim U[-1,1], Y=X^2, a.s.$
On one hand,
$$
f_{X|Y}(x | y) =
\frac 12 \left( \delta(x+\sqrt y) + \delta(x-\sqrt y) \right)
$$
$$
f_Y(y) = \frac{1}{2\sqrt y}
$$
On the other hand,
$$
F_{X,Y} (x,y) = \Pr(X\leqslant x, X^2\leqslant y)=
\Pr\left(-\sqrt y \leqslant X\leqslant \min(x,\sqrt y)\right) \\
= \begin{cases}
\frac{x+\sqrt{y}}{2}, & x < \sqrt y\\
\sqrt y, & x>\sqrt y
\end{cases}\\
= \frac{x+\sqrt y}{2} - \frac{x-\sqrt y}{2} u(x-\sqrt y)
$$
We want to show that
$$
f_{X,Y} (x,y) = f_{X|Y} (x|y) f_Y(y)
$$
But the link I provided did not discuss the multivariate distribution case. Getting $f_{X,Y} (x,y)$ involves taking the derivative of $F_{X,Y}(x,y)$ w.r.t. to $x$ and $y$, which in term requires the derivative of the delta function. I only found this: https://en.wikipedia.org/wiki/Unit_doublet but there is little information.