Let $L$ be a set of all bounded sequences of $\mathbb{R}$. Then it is easy to show that $L$ is a vector space with respect to normal addition and scalar multiplication. Define a function on $L \times L$ given by $$\langle(a_i) , (b_i)\rangle = \sum _{i = 1}^{\infty} {\frac{a_i b_i}{i^2}}.$$
Verifying that the above function is an inner product (scalar product) is a routine calculation.
The orthogonal complement of a subset $U$ of a vector space $L$ is $\,$ $U^* = \{\, A\in L: \, \langle A,B\rangle = 0 \, \text{and}\, \,\text{ for any} \,B\in U \,\}$.
If vector space is finite dimensional and $\,U$ is subspace then we have many nice properties like $U^{**} = U \,$ and any vector in vector space can be written uniquely as sum of vectors $U$ and $U^*$ and many more. Here we observe that if $U$ is a subspace then $U^*$ cannot be $\{ 0\}$ because the orthogonal complement of $\{0\}$ is vector space itself.
Here obviously $L$ is not a finite dimensional vector space. Is there any proper non zero subspace of $L$ whose orthogonal complement is $\{0\}$ ?