Perhaps you are confusing two probabilities.
First there is the probability that a particular coin when flipped shows heads. This is 50% for the fair coin and 75% for the biased coin. This probability does not change unless something about the coin is changed. So, for example, even after flipping the fair coin 100 times and getting 100 heads, the probability that the next flip will be heads is still 50%.
Second there is the probability that the coin you have been given is the biased coin. This is a measure of your confidence about which coin you have been given. If you get more information your confidence about which one it is may change. For example, if you learn that the fair coin is silver and the biased coin is bronze then you can become 100% confident about which coin you have just by looking at it. The coin doesn't change - it is your confidence about which coin you've been given which changes.
Initially you have no reason to believe that the coin is fair or biased. All you know is that it must be one or the other, the coins look identical, and it is equally likely to be either. So you assess the probability that it is biased to be 50%. This is clearly different to the probability that the coin will show heads when flipped.
Now you flip the coin 20 times and get 18 heads. You have gained some information about the coin in your possession. This increases your confidence that it is the biased coin because this outcome is more consistent with it being the biased coin. You might now be 90% confident that it is the biased coin. But you cannot be 100% sure because this outcome is also possible - but highly unlikely - if the coin is fair.