Your problem is convergence.
Ordinary continued fractions are well-behaved objects because we can truncate them at various points, getting a sequence of rational numbers, which (at least assuming all coefficients are positive integers) converge to some limit. Extending the truncation has a smaller and smaller effect on the final value.
In your backwards continued fractions, that is pretty much never going to be the case. If we truncate stopping at $b_n$, then for the $n^{\text{th}}$ approximation and the $(n-1)^{\text{th}}$ approximation to both be approximately equal to some value $x$, we want $x \approx b_n + \frac{a_n}{x}$, which is just a quadratic condition on $x$, $a_n$, and $b_n$ that ignores the rest of the continued fraction. Similar behavior happens if we truncate stopping at $a_n$. As a result, we don't get convergence unless $a_n$ and $b_n$ approach some specific relationship involving the limit; in particular, if the $a_n$ and $b_n$ are all integers, we can only converge to $x$ if $x$ is the root of a monic quadratic equation with integer coefficients, and we can only converge to it if $a_n$ and $b_n$ eventually are those integer coefficients.