We wish to prove the following equivalence.
Proposition (Sylvester's criterion)
Let $\mathbf{A} \in \mathbb{C}^{n \times n}$ be Hermitian. Then, $\mathbf{A}$ is positive definite if and only if all leading submatrices of $\mathbf{A}$ have a strictly positive determinant.
Proposition (Block LDU decomposition) A two by two block matrix $\mathbf{A}$ has the block LDU decomposition
\begin{equation}
\mathbf{A}
=
\begin{bmatrix}
\mathbf{A}_{11} & \mathbf{A}_{12} \\
\mathbf{A}_{21} & \mathbf{A}_{22}
\end{bmatrix}
=
\begin{bmatrix}
\mathbf{A}_{11} & \mathbf{0} \\
\mathbf{A}_{21} & \mathbf{I}
\end{bmatrix}
\begin{bmatrix}
\mathbf{I} & \mathbf{0} \\
\mathbf{0} & \mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^{-1} \mathbf{A}_{12}
\end{bmatrix}
\begin{bmatrix}
\mathbf{I} & \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{0} & \mathbf{I}
\end{bmatrix}
=
\mathbf{L}\mathbf{D}\mathbf{U},
\end{equation}
assuming that $\mathbf{A}_{11}$ is invertible. Furthermore,
\begin{equation}
\det(\mathbf{A}) = \det(\mathbf{A}_{11}) \det(\mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^{-1} \mathbf{A}_{12}).
\end{equation}
Motivation. Let's perform block Gauss-Jordan elimination on $\mathbf{A}$. First, perform a row operation $\mathbf{R}_1$ to set $\mathbf{A}_{11}$ to $\mathbf{I}$,
\begin{equation}
\mathbf{R}_1 \mathbf{A} =
\begin{bmatrix}
\mathbf{A}_{11}^{-1} & \mathbf{0} \\
\mathbf{0} & \mathbf{I}
\end{bmatrix}
\begin{bmatrix}
\mathbf{A}_{11} & \mathbf{A}_{12} \\
\mathbf{A}_{21} & \mathbf{A}_{22}
\end{bmatrix}
=
\begin{bmatrix}
\mathbf{I} & \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{A}_{21} & \mathbf{A}_{22}
\end{bmatrix}.
\end{equation}
Then, perform a row operation $\mathbf{R}_2$ to set the entry below the pivot $\mathbf{I}$ to zero,
\begin{equation}
\mathbf{R} \mathbf{A} := \mathbf{R}_2 \mathbf{R}_1 \mathbf{A} =
\begin{bmatrix}
\mathbf{I} & \mathbf{0} \\
-\mathbf{A}_{21} & \mathbf{I}
\end{bmatrix}
\begin{bmatrix}
\mathbf{I} & \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{A}_{21} & \mathbf{A}_{22}
\end{bmatrix}
=
\begin{bmatrix}
\mathbf{I} & \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{0} & \mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^{-1} \mathbf{A}_{12}
\end{bmatrix}.
\end{equation}
And finally, perform a column operation $\mathbf{C}$ to set the entry right of the pivot $\mathbf{I}$ to zero,
\begin{equation}
\mathbf{R} \mathbf{A} \mathbf{C} :=
\begin{bmatrix}
\mathbf{I} & \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{0} & \mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^{-1} \mathbf{A}_{12}
\end{bmatrix}
\begin{bmatrix}
\mathbf{I} & - \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{0} & \mathbf{I}
\end{bmatrix}
=
\begin{bmatrix}
\mathbf{I} & \mathbf{0} \\
\mathbf{0} & \mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^{-1} \mathbf{A}_{12}
\end{bmatrix}
=: \mathbf{D}.
\end{equation}
This yields the block reduced row echelon form $\mathbf{D}$. Notice that
\begin{equation}
\mathbf{A} = \mathbf{R}^{-1} \mathbf{R} \mathbf{A} \mathbf{C} \mathbf{C}^{-1} = \mathbf{R}^{-1} \mathbf{D} \mathbf{C}^{-1} = \mathbf{L} \mathbf{D} \mathbf{U}.
\end{equation}
Indeed, one can show that $\mathbf{L} = \mathbf{R}^{-1} = \mathbf{R}_1^{-1} \mathbf{R}_2^{-1}$ and $\mathbf{U} = \mathbf{C}^{-1}$ are the matrices of the proposition.
Proof. We check
\begin{equation}
\begin{aligned}
\mathbf{L}\mathbf{D}\mathbf{U}
&=
\begin{bmatrix}
\mathbf{A}_{11} & \mathbf{0} \\
\mathbf{A}_{21} & \mathbf{I}
\end{bmatrix}
\begin{bmatrix}
\mathbf{I} & \mathbf{0} \\
\mathbf{0} & \mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^{-1} \mathbf{A}_{12}
\end{bmatrix}
\begin{bmatrix}
\mathbf{I} & \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{0} & \mathbf{I}
\end{bmatrix} \\
&=
\begin{bmatrix}
\mathbf{A}_{11} & \mathbf{0} \\
\mathbf{A}_{21} & \mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^{-1} \mathbf{A}_{12}
\end{bmatrix}
\begin{bmatrix}
\mathbf{I} & \mathbf{A}_{11}^{-1} \mathbf{A}_{12} \\
\mathbf{0} & \mathbf{I}
\end{bmatrix} \\
&=
\begin{bmatrix}
\mathbf{A}_{11} & \mathbf{A}_{12} \\
\mathbf{A}_{21} & \mathbf{A}_{22}
\end{bmatrix} = \mathbf{A}.
\end{aligned}
\end{equation}
The determinant
\begin{equation}
\det(\mathbf{A}) = \det(\mathbf{L}\mathbf{D}\mathbf{U}) = \det(\mathbf{L})\det(\mathbf{D})\det(\mathbf{U}) = \det(\mathbf{A}_{11}) \det(\mathbf{A}_{22} - \mathbf{A}_{21} \mathbf{A}_{11}^\mathrm{T} \mathbf{A}_{12}).
\end{equation}
This concludes our proof.
Proposition (Sylvester's criterion)
Let $\mathbf{A} \in \mathbb{C}^{n \times n}$ be Hermitian. Then, $\mathbf{A}$ is positive definite if and only if all leading submatrices of $\mathbf{A}$ have a strictly positive determinant.
Proof. Consider a Hermitian matrix $\mathbf{A} \in \mathbb{C}^{n \times n}$.
( $\Longrightarrow$ ) Let $\mathbf{A}$ be positive definite. Then, for any leading submatrix $\mathbf{A}_k := \mathbf{A}_{1:k,1:k}$ of $\mathbf{A}$, for any non-zero vector $\mathbf{x}_k \in \mathbb{C}^{n} \setminus \{\mathbf{0}\}$, we have
\begin{equation}
0 <
\begin{bmatrix}
\mathbf{x}_k^* & \mathbf{0}
\end{bmatrix}
\mathbf{A}
\begin{bmatrix}
\mathbf{x}_k \\
\mathbf{0}
\end{bmatrix}
=
\mathbf{x}_k^* \mathbf{A}_k \mathbf{x}_k,
\end{equation}
so $\mathbf{A}_k$ is positive definite as well. As all eigenvalues of the positive definite matrix $\mathbf{A}_k$ are strictly positive (why?), and the determinant $\det(\mathbf{A}_k) := \prod_{i=1}^k \lambda_i$ is the product of the eigenvalues (why?), we have that $\det(\mathbf{A}_k) > 0$. Hence, all leading submatrices of $\mathbf{A}$ have a strictly positive determinant.
( $\Longleftarrow$ ) We proceed by induction on the size $n$ of a Hermitian matrix $\mathbf{A} \in \mathbb{C}^{n \times n}$.
( Base case ) Consider a matrix $[a_{11}] = \mathbf{A} \in \mathbb{C}^{1 \times 1}$ such that $\det(\mathbf{A}) > 0$. As $\mathbf{A}$ is Hermitian, $[a_{11}] = \mathbf{A} = \mathbf{A}^* = [\overline{a}_{11}]$ and $a_{11} \in \mathbb{R}$. And, as $a_{11} = \det(\mathbf{A}) > 0$, the matrix $\mathbf{A}$ is trivially positive definite.
( Induction hypothesis ) Suppose that the proposition holds for matrices of size $n = k-1$.
( Induction step ) Let $\mathbf{A} \in \mathbb{C}^{k \times k}$ be a matrix of size $n=k$ such that all leading submatrices of $\mathbf{A}$ have a strictly positive determinant. As $\mathbf{A}$ is Hermitian, we can partition $\mathbf{A}$ as (why?)
\begin{equation}
\mathbf{A} =
\begin{bmatrix}
\mathbf{A}_{k-1} & \mathbf{c} \\
\mathbf{c}^* & a_{kk}
\end{bmatrix},
\end{equation}
where $\mathbf{A}_{k-1} \in \mathbb{C}^{(k-1) \times (k-1)}$, $\mathbf{c} \in \mathbb{C}^{k-1}$ and $a_{kk} \in \mathbb{C}$. All leading submatrices of $\mathbf{A}_{k-1}$ have a strictly positive determinant, and by the induction hypothesis, $\mathbf{A}_{k-1}$ is positive definite. Furthermore, positive definite implies invertible (why?), so $\mathbf{A}_{k-1}$ is invertible, and by the block LDU decomposition, we have
\begin{equation}
\det(\mathbf{A}) = \det(\mathbf{A}_{k-1}) \det(a_{nn} - \mathbf{c}^* \mathbf{A}_{k-1}^{-1} \mathbf{c})
\end{equation}
or
\begin{equation}
a_{nn} - \mathbf{c}^* \mathbf{A}_{k-1}^{-1} \mathbf{c} = \frac{\det(\mathbf{A})}{\det(\mathbf{A}_{k-1})} > 0.
\end{equation}
We use this fact in the following. For any $\mathbf{x} \in \mathbb{C}^n \setminus \{\mathbf{0}\}$,
\begin{equation}
\begin{aligned}
\mathbf{x}^* \mathbf{A} \mathbf{x}
&=
\begin{bmatrix}
\mathbf{x}_{k-1}^* & \overline{x}_{n}
\end{bmatrix}
\begin{bmatrix}
\mathbf{A}_{k-1} & \mathbf{c} \\
\mathbf{c}^* & a_{kk}
\end{bmatrix}
\begin{bmatrix}
\mathbf{x}_{k-1} \\
x_n
\end{bmatrix} \\
&=
\mathbf{x}_{k-1}^* \mathbf{A}_{k-1} \mathbf{x}_{k-1} + \mathbf{x}_{k-1}^* \mathbf{c} x_n + \overline{x}_n\mathbf{c}^* \mathbf{x}_{k-1} + \vert x_n \vert^2 a_{kk}.
\end{aligned}.
\end{equation}
To employ positive definiteness of $\mathbf{A}_{k-1}$, we wish to write $\mathbf{x}^* \mathbf{A} \mathbf{x}$ in terms of
\begin{equation}
(\mathbf{x}_{k-1} + \mathbf{b})^* \mathbf{A}_{k-1} (\mathbf{x}_{k-1} + \mathbf{b}) = \mathbf{x}_{k-1}^* \mathbf{A} \mathbf{x}_{k-1} + \mathbf{x}_{k-1}^* \mathbf{A}_{k-1} \mathbf{b} + \mathbf{b}^* \mathbf{A}_{k-1} \mathbf{x}_{k-1} + \mathbf{b}^* \mathbf{A}_{k-1} \mathbf{b}^*,
\end{equation}
for the appropriate vector $\mathbf{b} \in \mathbb{C}^{(k-1)}$. It seems reasonable to take
\begin{equation}
\mathbf{x}_{k-1}^* \mathbf{A}_{k-1} \mathbf{b} = \mathbf{x}_{k-1}^* \mathbf{c} x_n
\end{equation}
or
\begin{equation}
\mathbf{b} = \mathbf{A}_{k-1}^{-1} \mathbf{c} x_n.
\end{equation}
Then,
\begin{equation}
\mathbf{b}^* \mathbf{A} \mathbf{b} = \overline{x}_n \mathbf{c}^* \mathbf{A}_{k-1}^{-*} \mathbf{A}_{k-1} \mathbf{A}_{k-1}^{-1} \mathbf{c} x_n = \vert x_n \vert^2 \mathbf{c}^* \mathbf{A}_{k-1}^{-1} \mathbf{c},
\end{equation}
and we can write
\begin{equation}
\mathbf{x}^* \mathbf{A} \mathbf{x} = \underbrace{(\mathbf{x}_{k-1} + \mathbf{b})^* \mathbf{A}_{k-1} (\mathbf{x}_{k-1} + \mathbf{b})}_{>0} + \underbrace{\vert x_n \vert^2 (a_{kk} - \mathbf{c}^* \mathbf{A}_{k-1}^{-1} \mathbf{c})}_{\geq 0},
\end{equation}
where the first term is strictly larger then zero as $\mathbf{A}_{k-1}$ is positive definite, and where the second term is positive by the argument above. Hence, we conclude that $\mathbf{A}$ is positive definite as well.
Finally, by induction, for any Hermitian matrix $\mathbf{A} \in \mathbb{C}^{n \times n}$ of any size, if all principal submatrices have a strictly positive determinant, then $\mathbf{A}$ is positive definite.